Droplet-based microfluidic systems have been shown to be compatible with many chemical and biological reagents and capable of performing a variety of operations that can be rendered programmable and reconfigurable.
AbstractMicrofluidics is an emerging branch of science that has significant applications in various fields. In this review paper, after a brief introduction to the concept of photocatalysis, nanoparticle preparation methods and film formation techniques have been studied. Nanoparticle synthesis in microfluidic systems and microreactor types for on-chip photocatalyst synthesis and challenges of nanoparticles handling in microsystems have been reviewed. To resolve particle polydispersity and microchannel clogging, a good suggestion can be the use of droplet-based microreactors. The configurative designs for the microfluidic reactor with immobilized photocatalysts, their applications, and their challenges have been comprehensively addressed. The three main challenges ahead the immobilized photocatalytic microfluidic reactors are optimal light distribution, prevention of the recombination of photogenerated electrons and holes, and improved mass transfer. Internal light-emitting diodes with a waveguide can resolve the number one challenge of photocatalysis application in optofluidic reactors, that is, light distribution.
With recent rapid urbanization, sustainable development is required to prevent health risks associated with adverse environmental exposures from the unsustainable development of cities. Ambient air pollution is the greatest environmental risk factor for human health and is responsible for considerable levels of mortality worldwide. Burden of disease assessment (BoD) of air pollution in and across cities, and how these estimates vary according to socioeconomic status and exposure to road traffic, can help city planners and health practitioners to mitigate adverse exposures and promote public health. In this study, we quantified the health impacts of air pollution exposure (PM2.5 and NO2) at the census tract level in Houston, Texas, employing a standard BoD assessment framework to estimate the premature deaths (adults 30 to 78 years old) attributable to PM2.5 and NO2. We found that 631 (95% CI: 366–809) premature deaths were attributable to PM2.5 in Houston, and 159 (95% CI: 0-609) were attributable to NO2, in 2010. Complying with the World Health Organization air quality guidelines (annual mean: 10 μg/m3 for PM2.5) and the US National Ambient Air Quality standard (annual mean: 12 μg/m3 for PM2.5) could save 82 (95% CI: 42–95) and 8 (95% CI: 6–10) lives in Houston, respectively. PM2.5 was responsible for 7.3% of all-cause premature deaths in Houston, in 2010, which is higher than the death rate associated with diabetes mellites, Alzheimer’s disease, or motor vehicle crashes in the US. Households with lower income had a higher risk of adverse exposure and attributable premature deaths. We also showed a positive relationship between health impacts attributable to air pollution and road traffic passing through census tracts, which was more prominent for NO2.
Iron-modified titanium dioxide nanostructured catalyst was synthesized by sol-gel method. Due to the important impacts of surface properties on the catalytic activity, the catalyst surface is investigated. To have a complete characterization of the catalyst, TEM, SEM, XPS, XRF, XRD, BET, and TGA-DTA techniques were
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