Computationally driven design of an artificial metalloenzyme using supramolecular anchoring strategies of iridium complexes to alcohol dehydrogenase

Abstract

Artificial metalloenzymes (ArMs) confer non-biological reactivities to biomolecules, whilst taking advantage of the biomolecular architecture in terms of selectivity and of renewable origin. In particular, ArMs design by supramolecular anchoring...

How to rationally design homogeneous catalysts for efficient CO2 electroreduction?

“…Where the I (A) is the value of the catalytic current (directly given by the electrochemical workstation), α is the number of transferred electrons corresponding to the half-reaction that generates a molecule of a target product or consumes a molecule of target reactant (the reaction equation Coefficient of electrons), N (mol) is the number of catalytically active sites, 94 and F (C/mol) is the Faraday constant. 95 …”