The volatile constituents of twelve essential oils from Madagascar, namely those of Cinnamomum camphora (L.) Presl, Cinnamomum zeylanicum Blume (leaf oil), Hedychium¯avum Roxb., Helichrysum gymnocephalum Humbert, Helichrysum selaginifolium L., Lantana camara L., Pelargonium roseum Willd., Piper nigrum L., Ravensara aromatica Havozo (bark oil and leaf oil), Vetiveria zizanioides (L.) Nash ex Small and Zingiber ocinale Roscoe were identi®ed and quanti®ed by high resolution capillary gas chromatography coupled to mass spectrometry (HRGC±MS) and high resolution capillary gas chromatography (HRGC), respectively. In all the essential oils at least one of the ®ve chiral monoterpenes citronellol, limonene, linalol, terpinen-4-ol and a-terpineol was detected. Analysis of the enantiomers using multidimensional capillary gas chromatography (MDGC) revealed speci®c enantiomeric excesses, except for linalol, which was found in racemic form in P. roseum essential oil.