“…The samples were directly infused into the Q-TOF using iterative MS/MS acquisition mode. The α-DCs were unambiguously identified according to their mass and production ions in agreement with published structural data ( Song et al, 2021 ). Nine different α-DCs including glucosone (GS), methylglyoxal (MGO), 2,3-pentosone (2,3-PS), 3-deoxyglucosone (3-DG), 1-deoxy-2,3-pentosulose (1-DP), 1,4-dideoxyglucosone (1,4-DDG), 1,4-dideoxy-2,3-diketopentose (1,4-DDP), 2,3-butanedione (2,3-BD) and 3,4-dideoxyglucosone-3-ene- (3,4-DGE) have been identified in the rape bee pollen samples.…”