This work reports
on the successful development of biopolypropylene/mango
peel flour (bioPP/MPF) composites using extrusion and injection molding
processes. The compatibility between bioPP and MPF is improved through
the use of PP-g-IA (3 phr) as a compatibilizer (which
is prepared by reactive extrusion REX) and dicumyl peroxide (DCP)
(1 phr) as a cross-linker. The mechanical, morphological, thermal,
thermomechanical, chemical, colorimetric, water absorption, and flowability
properties are characterized and analyzed. The results show that MPF
(30 wt %) compatibilized with PP-g-IA and DCP increased
the stiffness of bioPP in terms of Young’s modulus values.
Elongation at break also shows very promising results, with a maximum
value of almost 30% for the bioPP/MPF/PP-g-IA/DCP
sample. PP-g-IA and DCP seem to exert a synergetic
effect. Thermal stability is also improved as a result of these additives,
as well as crystallinity, which is increased due to an heterogeneous
nucleation phenomenon, enhanced by a higher dispersion of MPF particles
in the matrix. Moreover, the excellent mechanical results are verified
in FESEM images, where a very narrow gap between the MPF particles
and the bioPP matrix is appreciated.