Comparison of Chemical Properties and Application as Acid Soil Amendment of Pretreatment Center Slag and Other Slags

Abstract

Chemical properties of Pretreatment center slag (PTC-slag) were analyzed and compared to those of converter slag (C slag) and blast furnace slag (BF slag). PTC slag had a high EC value as well as citric acid soluble P and contained more Ca, Si, P, K, and Na but less Mg and Fe than C slag. Compared to BF slag, PTC slag contained more Fe, Ca, Mg, P, Mn, and Na but less Si, Al, and K. Although neutralizing value of PTC slag was lower than that of C slag, its ability to neutralize soilacidity was markedly higher. A pot experiment using Andisol from Tochigi Prefecture and komatsuna plant was carried outto evaluate PTC slag as liming material as well as P fertilizer. PTC slag, C slag, and dolomite were applied as liming materials and combined with super phosphate (SP). Addition of SP of 2.5 and 5.0% phosphate absorption coefficient (PAC) to PTC slag significantly improved the yield of komatsuna.This result, however, only apply for PTC slag adjusting soil pH to 6.5. Addit~ono f the same dosage of SP to PTC slag adjusting soil pH to 7.5 did not give significant effect. On the other hand, addition of SP of 2.5 and 5.0% PAC to C slag or dolomite significantly improved the yield for both C slag ordolomite adjusting. the soil pH to 6.5 and 7.5. Results of the experiment also indicated that P'TC slag and C slag significantly increased soil pH; exchangeable Ca, and Mg and improved available P, B, and Mn in Andisol. The magnitudes ofthese effects of the two slags, however, were difference. As compared to C slag and dolomite, PTC slag increased lower exchangeable Mg but higher available P. These results suggest that for acid soil amendment, PTC slag was better than dolomite and C slag due to the fact that this material supplymore P and B. Application of PTC slag as acid soil amendment will reduce the demand of P fertilizer, and even in high dosage can meet the P demand of komatsuna plant.

Effect of liming of sod-podzolic soils with by-products of steel production on soil acidity and composition of wash water (column experiments)

“…In the treatments with the use of BFS slag, this increase was higher due to the higher chemical activity of BFS slag. In addition, Suwarno et al (2001) found that both types of slag significantly increased soil pH; exchangeable Ca, and Mg in Andisol.…”

“…Similarly, Suwarno et al (2001) found that the magnitudes of the effects of the two slags were different.…”

“…Shilnikov et al (2011) comparing various types of studied liming materials found that the highest payback was found from the addition of metallurgical slag. Suwarno et al (2001) also found that application of metallurgical slag showed better effect on growing plants than traditional dolomite liming.…”

“…In addition to the decrease in acidity levels, Ca and Mg supply also occurs in soil (Torkashvand and Sedaghathoor 2007;Deus et al 2014;Mantovani et al, 2016). Suwarno et al, 2001) found that application of steel slag showed positive effect on plant growth compared to the dolomite liming that had no effect on P uptake by plants.…”