The removal of toxic heavy metals from wastewater through
the use
of novel adsorbents is expensive. The challenge arises after the heavy
metal is removed by the adsorbent, and the fate of the adsorbent is
not taken care of. This may create secondary pollution. The study
aimed to prepare mesoporous carbon (MC) from macadamia nutshells coated
with titanium dioxide nanoparticles (TiO2 NPs) using a
hydrothermal method to remove Pb2+ and to test the effectiveness
of reusing the lead-loaded spent adsorbent (Pb2+-MC/TiO2 NP nanocomposite) in blood fingerprint detection. The samples
were characterized using SEM, which confirmed spherical and flower-like
structures of the nanomaterials, whereas TEM confirmed a particle
size of 5 nm. The presence of functional groups such as C and Ti and
a crystalline size of 4 nm were confirmed by FTIR and XRD, respectively.
The surface area of 1283.822 m2/g for the MC/TiO2 NP nanocomposite was examined by BET. The removal of Pb2+ at pH 4 and the dosage of 1.6 g/L with the highest percentage removal
of 98% were analyzed by ICP-OES. The Langmuir isotherm model best
fit the experimental data, and the maximum adsorption capacity of
the MC/TiO2 NP nanocomposite was 168.919 mg/g. The adsorption
followed the pseudo-second-order kinetic model. The ΔH° (−54.783) represented the exothermic nature,
and ΔG° (−0.133 to −4.743)
indicated that the adsorption process is spontaneous. In the blood
fingerprint detection, the fingerprint details were more visible after
applying the Pb2+-MC/TiO2 NP nanocomposite than
before the application. The reuse application experiments showed that
the Pb2+-MC/TiO2 NP nanocomposite might be a
useful alternative material for blood fingerprint enhancement when
applied on nonporous surfaces, eliminating secondary pollution.