Abstract:More recently pellet‐based additive manufacturing or so‐called micro‐extrusion has become more popular for final polymeric part production. In the present work, it is evaluated how pellet‐based AM (PBAM) performs for its extrudates and specimens compared to the more established fused filament fabrication technique, considering both commercial acrylonitrile butadiene styrene polymer and poly(lactic acid) pellets and filaments as feedstocks. For benchmarking purposes, a comparison with conventional techniques, t… Show more
“…La Gala et al [202] recently compared the properties of ABS and PLA produced via FFF and PBAM. Via FTIR, a higher degree of degradation of ABS manufactured via FFF compared to PBAM has been reported.…”
The assessment of the extent of degradation of polymer molecules during processing via conventional (e.g., extrusion and injection molding) and emerging (e.g., additive manufacturing; AM) techniques is important for both the final polymer material performance with respect to technical specifications and the material circularity. In this contribution, the most relevant (thermal, thermo-mechanical, thermal-oxidative, hydrolysis) degradation mechanisms of polymer materials during processing are discussed, addressing conventional extrusion-based manufacturing, including mechanical recycling, and AM. An overview is given of the most important experimental characterization techniques, and it is explained how these can be connected with modeling tools. Case studies are incorporated, dealing with polyesters, styrene-based materials, and polyolefins, as well as the typical AM polymers. Guidelines are formulated in view of a better molecular scale driven degradation control.
“…La Gala et al [202] recently compared the properties of ABS and PLA produced via FFF and PBAM. Via FTIR, a higher degree of degradation of ABS manufactured via FFF compared to PBAM has been reported.…”
The assessment of the extent of degradation of polymer molecules during processing via conventional (e.g., extrusion and injection molding) and emerging (e.g., additive manufacturing; AM) techniques is important for both the final polymer material performance with respect to technical specifications and the material circularity. In this contribution, the most relevant (thermal, thermo-mechanical, thermal-oxidative, hydrolysis) degradation mechanisms of polymer materials during processing are discussed, addressing conventional extrusion-based manufacturing, including mechanical recycling, and AM. An overview is given of the most important experimental characterization techniques, and it is explained how these can be connected with modeling tools. Case studies are incorporated, dealing with polyesters, styrene-based materials, and polyolefins, as well as the typical AM polymers. Guidelines are formulated in view of a better molecular scale driven degradation control.
“…Regarding part material, acrylonitrile butadiene styrene (ABS) polymer is a very popular choice for FFF (Travieso-Rodriguez et al , 2021; La Gala et al , 2022). This is due to its physical properties such as impact resistance, tensile strength and stiffness.…”
Purpose
Fused filament fabrication (FFF) is a type of additive manufacturing (AM) based on materials extrusion. It is the most widely practiced AM route, especially used for polymer-based rapid prototyping and customized product fabrication in relation to aerospace, automotive, architecture, consumer goods and medical applications. During FFF, part quality (surface finish, dimensional accuracy and static mechanical strength) is greatly influenced by several process parameters. The paper aims to study FFF parametric influence on aforesaid part quality aspects. In addition, dynamic analysis of the FFF part is carried out.
Design/methodology/approach
Interpretive structural modelling is attempted to articulate interrelationships that exist amongst FFF parameters. Next, a few specimens are fabricated using acrylonitrile butadiene styrene plastic at varied build orientation and build style. Effects of build orientation and build style on part’s ultimate tensile strength, flexure strength along with width build time are studied. Prototype beams (of different thickness) are fabricated by varying build style. Instrumental impact hammer Modal analysis is performed on the cantilever beams (cantilever support) to obtain the natural frequencies (first mode). Parametric influence on natural frequencies is also studied.
Findings
Static mechanical properties (tensile and flexure strength) are greatly influenced by build style and build orientation. Natural frequency (NF) of prototype beams is highly influenced by the build style and beam thickness.
Originality/value
FFF built parts when subjected to application, may have to face a variety of external dynamic loads. If frequency of induced vibration (due to external force) matches with NF of the component part, resonance is incurred. To avoid occurrence of resonance, operational frequency (frequency of externally applied forces) must be lower/ higher than the NF. Because NF depends on mass and stiffness, and boundary conditions, FFF parts produced through varying build style may definitely correspond to varied NF. This aspect is explained in this work.
“…With its unique combination of versatility, precision, and costeffectiveness, DPAM holds the potential to become the new leading AM technique. Ongoing research and development in this field are expected to further enhance its capabilities, making it an essential tool for a wide range of manufacturing applications [3,17,21,[25][26][27].…”
Short carbon fiber (sCF)-based polymer composite parts enable one to increase in the material property range for additive manufacturing (AM) applications. However, room for technical and material improvement is still possible, bearing in mind that the commonly used fused filament fabrication (FFF) technique is prone to an extra filament-making step. Here, we compare FFF with direct pellet additive manufacturing (DPAM) for sCF-based composites, taking into account degradation reactions, print quality, and energy usage. On top of that, the matrix is based on industrial waste polymers (recycled polycarbonate blended with acrylonitrile butadiene styrene polymer and recycled propylene), additives are explored, and the printing settings are optimized, benefiting from molecular, rheological, thermal, morphological, and material property analyses. Despite this, DPAM resulted in a rougher surface finish compared to FFF and can be seen as a faster printing technique that reduces energy consumption and molecular degradation. The findings help formulate guidelines for the successful DPAM and FFF of sCF-based composite materials in view of better market appreciation.
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