One of the challenges for single-screw micro-extrusion or additive manufacturing (AM), thus 3D printing, of polymers is controlling the melting efficiency so that energy and equipment costs can be minimized. Here, a numerical model is presented for AM process design, selecting acrylonitrile–butadiene–styrene (ABS) as viscoelastic reference polymer. It is demonstrated that AM melting is different compared to conventional melting due to variation in extrusion dimensions, leading to a different balance in heating by conduction and viscous heat dissipation as caused by the shearing between the melt layers in the associated film layer near the barrel. The thickness of this melt film layer is variable along the screw length, and it is shown that simplified models assuming an overall average value are too approximate. It is highlighted that the screw frequency, pitch angle and compression ratio are important process parameters to control the point of melt finalization. In addition, the power-law index reflecting the shear thinning nature of the polymer melt is showcased as a key parameter. Moreover, AM process results assuming constant and temperature dependent specific heat capacities and thermal conductivities are compared. The current work opens the door for on-line AM process control, addressing all relevant operating and material parameters.
To improve the product quality of polymeric parts realized through extrusion-based additive manufacturing (EAM) utilizing pellets, a good control of the melting is required. In the present work, we demonstrate the strength of a previously developed melt removal using a drag framework to support such improvement. This model, downscaled from conventional extrusion, is successfully validated for pellet-based EAM—hence, micro-extrusion—employing three material types with different measured rheological behavior, i.e., acrylonitrile-butadiene-styrene (ABS), polylactic acid (PLA) and styrene-ethylene-butylene-styrene polymer (SEBS). The model’s validation is made possible by conducting for the first time dedicated EAM screw-freezing experiments combined with appropriate image/data analysis and inputting rheological data. It is showcased that the (overall) processing temperature is crucial to enable similar melting efficiencies. The melting mechanism can vary with the material type. For ABS, an initially large contribution of viscous heat dissipation is observed, while for PLA and SEBS thermal conduction is always more relevant. It is highlighted based on scanning electron microscopy (SEM) analysis that upon properly tuning the finalization of the melting point within the envisaged melting zone, better final material properties are achieved. The model can be further used to find an optimal balance between processing time (e.g., by variation of the screw frequency) and material product performance (e.g., strength of the printed polymeric part).
Purpose This study aims to evaluate and compare the macroscopic properties of commercial acrylonitrile-butadiene-styrene (ABS) processed by two different types of additive manufacturing (AM) machines. The focus is also on the effect of multiple closed-loop recycling of ABS. Design/methodology/approach A conventional direct-drive, Cartesian-type machine and a Bowden, Delta-type machine with an infrared radiant heating system are used to manufacture test specimens molded in ABS. Afterward, multiple closed-loop recycling cycles are conducted, involving consecutive AM (four times) and recycling (three times). The rheological, mechanical, morphological and physicochemical properties are investigated. Findings The type of machine affects the quality of the produced parts. The machine containing an infrared radiant system in a temperature-controlled chamber produces parts showing higher mechanical properties and filling fraction, although it increases the yellowing. Closed-loop recycling of ABS for AM is applicable for at least two cycles, inducing a slight increase in tensile modulus (ca. 5%) and in tensile strength (ca. 13%) and a decrease in the impact strength (ca. 14%) and melt viscosity. An increase in the filling fraction of the AM parts promotes an increase in tensile strength and tensile modulus, although it does not influence the impact strength. Furthermore, multiple closed-loop recycling does not affect the overall chemical structure of ABS. Practical implications Controlling the environmental temperature and using infrared radiant heating during AM of ABS improves the quality of the produced parts. Closed-loop recycling of ABS used in AM is feasible up to at least two recycling steps, supporting the implementation of a circular economy for polymer-based AM. Originality/value This study shows original results regarding the assessment of the effect of different types of AM machines on the main end-use properties of ABS parts and the influence of multiple closed-loop recycling on the characteristics of ABS fabricated by the most suited AM machine with an infrared radiant heating system and a temperature-controlled environment.
An important polymer processing technique is additive manufacturing (AM), which enables shape-free design of complex final parts with limited waste during the development change, at least if the impact of molecular degradation reactions is minimized. In the present work, polystyrene (PS) and acrylonitrile butadiene styrene (ABS) polymer have been processed via: (i) fused filament fabrication (FFF), separately accounting for the prior single screw extrusion (SSE) filament production; and (ii) pellet-based additive manufacturing (PBAM), which are two important AM techniques. The influence of printing temperature, layer thickness, printing velocity, and printing technique on the degradation of both polymeric materials is studied by means of thermogravimetric analysis (TGA), size exclusion chromatography (SEC), small amplitude oscillatory shearing tests (SAOS), Fourier-transform infrared spectroscopy (FTIR), and yellowness index (YI) measurements. For ABS, SSE-FF leads to more fission (higher mechanical loading) whereas PBAM results in more cross-linking (more thermal loading). For PS, fission is always dominant and this more evident under FFF conditions. ABS also exhibits yellowing upon processing, indicating thermo-oxidative degradation although below the FTIR sensitivity limit. The selected PBAM conditions with PS are already delivering printed specimens with good mechanical properties and lower degradation. For ABS, a further PBAM optimization is still desired compared to the FFF countercase, taking into account layer-by-layer adhesion.
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