In this work, the photovoltaic outputs of the lead-free FASnI 3 -based perovskite solar cells are discussed by using Solar Cell Capacitance Simulator in One Dimension. The device outputs estimated theoretically in this study are almost equal to the experimental results, thereby verifying accuracy of this simulation. To find the decent electron transport layer (ETL), herein, various ETLs are presented instead of C 60 /BCP in the experimental FASnI 3 -based perovskite solar cell (PSC). The designed FASnI 3 PSC utilizing niobium pentoxide (Nb 2 O 5 ) as an ETL with an appropriate band alignment and a low lattice mismatch at FASnI 3 /ETL interface provides better efficiency by decreasing recombination at front side. The performances of the proposed PSC are also measured by altering the thickness and doping of ETL and absorber, interface defects, and series and shunt resistances. Furthermore, this paper reports the calculation of recombination coefficients at absorber/ETL interface, depletion region, and quasi-neutral region. An improved efficiency of 22.24% is evaluated at optimized thicknesses of 100 nm for HTL, 500 nm for absorber, 50 nm for ETL, and 50