Comparative rates of exchange behind reflected shock waves. 2. 15NO + C18O vs. 15NO + N2

Abstract

greater than that of Figure 10. Thus, in general, for a given j?/T, tr computed via eq C2 will be slightly larger than that computed via the Wilson-Kivelson equations.Lastly, we note that there is no indication in these results on VO(acac)2 in toluene of any substantial departure of the spectral densities from Debye-type spectral densities (i.e., the definitions of µ and in eq C2 such as was found for PD-Tempone in toluene.12 This is, perhaps, consistent with the slow-motional result that ESR spectra of the vanadyl complexes are fit by Brownian diffusion while PD-Tempone is fit by jump diffusion.