Unsteady premixed and non-premixed counterflow laminar flame simulations were conducted in order to investigate extinction effects on observables commonly used in turbulent combustion. CH 4 and n-C 12 H 26 were the fuels studied, with air as the oxidizer at pressures of 1, 5, and 10 bar. It was determined that CH 2 O persists, compared to all other reactive species, during the extinction transient for both fuels and at all conditions, as the loss of OH concentration removes the dominant CH 2 O consumption pathway. The persistence of CH 2 O concentration is duplicated similarly in CH 4 and n-C 12 H 26 premixed flames. For non-premixed flames, the results indicate that the peak CH 2 O concentration reduction for n-C 12 H 26 flames is milder compared to CH 4 flames. Increasing the pressure causes an extension of reactivity, resulting in greater CH 2 O production and thus a delayed decay during the extinction transient. In addition, a change in the magnitude of the applied scalar dissipation rate for the non-premixed flames did not alter the trends of CH 2 O during extinction. Thus, caution is suggested when using CH 2 O in turbulent combustion experiments as a marker of the preheat zone thickness, given that increased levels of CH 2 O could be a result of multiple local extinction events. In addition, the product of OH and CH 2 O was found to scale well with the heat release rate for CH 4 and n-C 12 H 26 flames at multiple pressures. Finally, the CH* and OH* chemiluminescence was examined. CH* was found to extinguish slightly before the other species and more importantly, that once its concentration is reduced to a negligible level, the flame is on its way to extinction with no chance of recovery. OH* was determined to scale well with heat release at both 1 and 10 bar for both fuels and type of flames.