“…The frequency of the 3.39-µm He-Ne laser stabilized by methane lines was measured using several methods [6,7]; as a result, an optical frequency standard was designed [8,9,10,11,12] and several approaches for optical frequency combs stabilization were proposed [13,14,15,16]. To date, 10 much research has considered the methane P(7) line of the ν 3 band parameters at 3.39 µm [17,18]; however there are a number of lines in the mid-IR region that are free from magnetic hyperfine structures that have better prospects for use in laser frequency stabilization. The development of cw tunable solidstate lasers based on crystals of A 2 B 6 compounds doped with divalent ions 15 of transition metals [19,20,21] solved the problem of choosing appropriate lines [22,23,24].…”