Combining reversible addition-fragmentation chain transfer polymerization and thiol-ene click reaction for application of core-shell structured VO2@polymer nanoparticles to smart window

Zhao, Xiuxian; Sun, Junhua; Ma, Jiachen; Liu, Tongyao; Guo, Zeyi; Yang, Zhen; Yao, Wei; Jiang, Xuchuan

doi:10.1016/j.susmat.2022.e00420

Cited by 7 publications

(3 citation statements)

References 51 publications

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“…Different functional groups, such as halogen atoms, can be attached to commonly used polymer chains to realize several fascinating inherent properties. For instance, F‐containing polymers can be stabilized in strong acid and alkali solutions owing to the high electronegativity of F. [ 130 ] Such wide pH adaptation is expected to endow the flexible Zn–air batteries with stable operation in the entire pH environment. At the same time, the rapid development of machine learning and high‐throughput experiments can also help to screen potential candidate polymer materials and organic solvents from massive material databases.…”

Section: Summary and Perspectivesmentioning

confidence: 99%

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

et al. 2023

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With growing demands for portable electronics, flexible aqueous energy storage devices such as supercapacitors and Zn‐based batteries have drawn tremendous interest from both academic and industrial fields. Organo‐hydrogels, crosslinked amphiphilic polymers filled with organic solvents and water, are regarded as an ideal electrolyte candidate for portable electronic applications, especially due to their superior environmental adaptation. Organo‐hydrogels can reserve the advantages of the corresponding hydrogels and achieve some unique features such as broad temperature tolerance, high mechanical stability, strong interfacial interaction, and decent ionic conductivity. This review outlines the composition fundamentals, preparation methods, and comprehensive properties of reported organo‐hydrogel electrolytes. In particular, supercapacitors and Zn‐based batteries that operate under harsh temperature conditions and unusual mechanical deformations endowed by organo‐hydrogel electrolytes are further highlighted. Moreover, a unique perspective on the current challenges and future development directions of the organo‐hydrogel electrolytes for flexible energy storage is also provided.

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Section: Summary and Perspectivesmentioning

confidence: 99%

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

et al. 2023

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“…[27,28] Thermochromic smart windows are highly competitive among different response modes due to their unique features such as low cost, simple structure, passivity, and reasonable stimulus-response. [29,30] Currently, various thermal response materials have been successfully applied, including vanadium dioxide (VO 2 ), [31][32][33][34][35][36][37] hydrogels (poly-N isopropyl acrylamide (PNIPAm), [38,39] hydroxypropyl cellulose (HPC), [40,41] N-vinyl caprolactam (PNVCL), [42] and other types. [9,32,[43][44][45][46][47] Among them, most research interests in thermochromic smart windows mainly focus on VO 2 .…”

Section: Introductionmentioning

confidence: 99%

“…Smart windows are categorized based on different stimuli, including heat, [9–13] electricity, [14–20] light, [21–26] and humidity [27,28] . Thermochromic smart windows are highly competitive among different response modes due to their unique features such as low cost, simple structure, passivity, and reasonable stimulus‐response [29,30] . Currently, various thermal response materials have been successfully applied, including vanadium dioxide (VO 2 ), [31–37] hydrogels (poly‐N isopropyl acrylamide (PNIPAm), [38,39] hydroxypropyl cellulose (HPC), [40,41] N‐vinyl caprolactam (PNVCL), [42] and other types [9,32,43–47] .…”

Section: Introductionmentioning

confidence: 99%

VO₂ Nanoparticles‐Based Thermochromic Smart Windows

Zhou,

Zhao,

et al. 2023

ChemistrySelect

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Vanadium dioxide (VO2) has reversible metal‐to‐insulator phase transitions (MIT) under thermal stimuli, which is a traditional and widely studied material for thermochromic smart window applications. Current research interests in VO2 materials design focused on decreasing phase change temperature (τc), increasing both luminous transmittance (Tlum) and solar modulating ability (▵Tsol). This review focuses on strategies for improving the thermochromic properties of VO2, including elemental doping to composite materials, improving the solar energy modulation ability, ameliorating color, elevating phase change efficiency, increasing durability, and enhancing energy efficiency. The challenges and opportunities of VO2 nanoparticles‐based thermochromic smart windows are discussed in the outlook section.

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An Interesting Functional Phase Change Material VO₂: Response to Multivariate Control and Extensive Applications in Optics and Electronics

Liu,

Chai

et al. 2023

Adv Elect Materials

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Under physical conditions such as TC = 68 °C, Vanadium dioxide (VO2) undergoes a reversible transformation from a monoclinic phase to a tetragonal rutile phase. This transformation is accompanied by a series of changes in physical properties, including transmittance, conductivity, and refractive index, which make it an excellent functional material. Based on this, VO2 has been extensively researched and applied in the fields of electronics and optics, yielding remarkable results and making it a hot research material. This paper reviews the phase transition mechanisms and optical/electrical properties of VO2, as well as its phase transition hysteresis. From the application perspective, this paper summarizes the modulation content under various external excitations and the element doping effects. Finally, this paper summarizes the classic VO2‐based devices, and points out the development direction and potential of VO2 in optics and electronics. This review provides a systematic summary of VO2, which is useful for its practical applications.

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Combining reversible addition-fragmentation chain transfer polymerization and thiol-ene click reaction for application of core-shell structured VO2@polymer nanoparticles to smart window

Cited by 7 publications

References 51 publications

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

VO₂ Nanoparticles‐Based Thermochromic Smart Windows

An Interesting Functional Phase Change Material VO₂: Response to Multivariate Control and Extensive Applications in Optics and Electronics

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Combining reversible addition-fragmentation chain transfer polymerization and thiol-ene click reaction for application of core-shell structured VO2@polymer nanoparticles to smart window

Cited by 7 publications

References 51 publications

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

Organo‐Hydrogel Electrolytes with Versatile Environmental Adaptation for Advanced Flexible Aqueous Energy Storage Devices

VO2 Nanoparticles‐Based Thermochromic Smart Windows

An Interesting Functional Phase Change Material VO2: Response to Multivariate Control and Extensive Applications in Optics and Electronics

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Product

Resources

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VO₂ Nanoparticles‐Based Thermochromic Smart Windows

An Interesting Functional Phase Change Material VO₂: Response to Multivariate Control and Extensive Applications in Optics and Electronics