2013
DOI: 10.15376/biores.8.4.6087-6096
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Combination of Glyoxal and Chitosan as the Crosslinking System to Improve Paper Wet Strength

Abstract: The wet strength of handsheets subjected to dipping treatment by solutions such as glyoxal with Zn(NO 3 ) 2 as a catalyst, chitosan, and the crosslinking system of glyoxal and chitosan is studied in this paper. The crosslinking system achieved better wet strength performance than glyoxal or chitosan alone and slightly better than the sum of glyoxal and chitosan in the case of a curing temperature between 90 and 130 o C. However, handsheets treated by this crosslinking system became more brittle, which was show… Show more

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Cited by 6 publications
(6 citation statements)
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References 18 publications
(21 reference statements)
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“…Chitosan or its derivatives are added to water-suspended paper pulp mixture with non-fibrous additives furnish [7,8] or used for coating paper [9][10][11] to obtain packaging papers with improved tensile and burst strength properties. The wet and dry tensile strength values of recycled corrugated carton pulp were improved by different dosages of high-molecular-weight Chitosan [12].…”
Section: Introductionmentioning
confidence: 99%
“…Chitosan or its derivatives are added to water-suspended paper pulp mixture with non-fibrous additives furnish [7,8] or used for coating paper [9][10][11] to obtain packaging papers with improved tensile and burst strength properties. The wet and dry tensile strength values of recycled corrugated carton pulp were improved by different dosages of high-molecular-weight Chitosan [12].…”
Section: Introductionmentioning
confidence: 99%
“…The liquid phase was removed by a sand core funnel and the remained filamentous precipitate was washed with an excess amount of 95% (v/v) ethanol to neutral pH. The white powder was dried under vacuum at 55 °C for 12 h …”
Section: Methodsmentioning
confidence: 99%
“…The titration end point was obtained when the red color of the mixture vanished for 30 s and did not appear again. The degree of substitution of MAC was calculated by using Equation Dnormals=167.09×W100×99(991)×W×100where D s (%) is the degree of substitution of MAC, 167.09 (g mol −1 ) is the mean relative molecular mass of the chitosan unit with 87% deacetylation, and W (%) is the mass percent of substituent. W is determined using Equation W=(c1v1c2v2)×103×Mm×100where M is the relative molecular mass of maleic acid group, m is the mass of MAC sample; c 1 (mol L −1 ) and v 1 (L) are the molar concentration and volume of NaOH standard aqueous solution, and c 2 (mol L −1 ) and v 2 (L) are the molar concentration and consumed volume of HCl standard aqueous solution.…”
Section: Methodsmentioning
confidence: 99%
“…It has been used as a papermaking additive and for the surface treatment of paper for decades. Chitosan graft copolymers have been exploited for making paper products of improved dry strength, and chitosan has been added to cellulose and unbleached sulfite to increase the burst, dry-tensile, and wet-tensile properties of handsheets [2527]. Its use has been recommended for the manufacture of electric insulation papers and various types of technical papers, particularly wet-strength papers.…”
Section: Introductionmentioning
confidence: 99%