“…The solvent was removed to afford the product as dark red crystals that were recrystallized from chloroform to afford 1.30 g, (59 %). 1 Poly(2,7-(9-(2¢-ethylhexyl)-9-hexyl-fluorene)-alt-5,5-(4¢,7¢-di-2-thienyl-2¢,1¢,3¢-benzothiadiazole)) (PFDTBT): 4,7-Di-2¢-(5¢-bromo)-thienyl-2,1,3-benzothiadiazole (0.15 g, 0.33 mmol) was mixed with 2,7-bis(4¢,4¢,5¢,5¢-tetramethyl-1¢,3¢,2¢-dioxaborolan-2¢-yl)-9-(2¢¢-ethylhexyl)-9-hexylfluorene (0.22 g, 0.36 mmol, 1.1 equiv), tetrakis(triphenylphosphine)Pd(0) (3.0 mg, 2.6 lmol) and toluene (6 mL) and refluxed for 10 min under N 2 . Tetraethylammonium hydroxide (1.0 mL, 20 wt.-% in water, 1.4 mmol) was added with a syringe and the mixture was refluxed for 2.5 h. Bromobenzene (0.05 g, 0.32 mmol) was added and after 1 h reflux phenylboronic acid (0.06 g, 0.5 mmol) was added.…”