at the measuring facility of the mid-latitude geophysical observatory "Borok" (Yaroslavsl' Region, Russia), we conclude that correlative relations exist between the aeroelectric-field intensity E and the air temperature T in the atmospheric surface layer. We reveal positive correlation between the temperature and electric-field variations under conditions of unstable stratification (late morning-day) and negative correlation under stable stratification (late evening-night). A simultaneous increase in the amplitude of pulsations of the electric field and the temperature occurs most frequently near the local midday. Intense variations in the electric field correspond to variations in the temperature field with a close time period. A positive temporal shift of variations in E with respect to variations in T , which reaches 40 min, is observed during enhanced temperature activity. The structure-temporal analysis of experimental data from remote sensing of the temperature and electric-field variations at five points is performed. We find simultaneous aeroelectric and temperature coherent structures accompanied by short-period pulsations of the field intensity and the air temperature in the atmospheric surface layer.We discuss possible mechanisms of coupling of the aeroelectric-field intensity and the atmospheric air temperature to describe their positive correlation under conditions of unstable stratification (late morning-day) and negative correlation in the late evening and at night. Enhancement of electric activity, which is stipulated by the intensification of turbulent convection and the formation of aeroelectric structures, seems the most significant process. With allowance for nonlocality of the electric field, this process can in particular explain a substantial lead of the aeroelectric-field perturbations compared with the correlated positive temperature perturbations. In this case, the formation of warm "quasi-front," which is accompanied by the lifting of the nearsurface air abundant in moisture and charged particles to the higher atmospheric layers, can play an important role. Other mechanisms of the field-temperature coupling take into account a decrease in the conductivity of near-surface air due to the condensation of water vapor during its cooling, as well as an increase in the mobility of light ions with increasing air temperature.