To enhance the functionality of the standard silicon photonics platform and to overcome its limitations, in particular for light emission, ultrafast modulation and non-linear applications, integration with novel materials is being investigated by several groups. In this paper we will discuss, amongst others, the integration of silicon waveguides with ferroelectric materials such as PZT and BTO, with electro-optically active polymers, with 2Dmaterials such as graphene and with III-V semiconductors through epitaxy. We discuss both the technology and design aspects.