Coating of unreactive and reactive surfaces by aluminosilicate binder

Vidal, L.; Joussein, Emmanuel; Absi, Joseph; Rossignol, Sylvie

doi:10.1016/j.ceramint.2016.10.140

Cited by 7 publications

(1 citation statement)

References 35 publications

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“…Normally, inorganic coating can be categorized based on the main membrane substances, for example, silicates, colloidal silica and phosphate, etc. Recently, some studies have reported that geopolymer prepared by alkali-activated technology could be used to produce coatings [1][2][3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Property and Microstructure of Waterborne Self-Setting Geopolymer Coating: Optimization Effect of SiO2/Na2O Molar Ratio

Liu

et al. 2018

Minerals

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As a kind of coating material, the inorganic coating of alkali-activated metakaolin geopolymer cured at high temperature has been studied a lot for special applications. To our best knowledge, however, not much attention has been given to investigate the influence of SiO 2 /Na 2 O molar ratio on property of the geopolymer coating. This paper is, thus, dedicated to investigate the role of SiO 2 /Na 2 O molar ratio on property and microstructure of metakaolin-based geopolymer coating at ambient temperature. The effects on setting behavior, adhesive strength, shrinkage deformation and permeability are discussed. Multiple experiments were used to reveal microstructure changes of the geopolymer coating with different ratios of SiO 2 /Na 2 O, including Mercury Intrusion Porosimetry (MIP), Scanning Electron Microscope (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The results indicated that the optimal ratio of SiO 2 /Na 2 O was 1.0 for good properties of adhesive strength, shrinkage and impermeability. In addition, it has been found that the setting time of geopolymer coating increased with SiO 2 /Na 2 O ratio which increased from 0.8 to 1.5. That agrees well with the other property and results of exothermal rate of alkali-activated metakaolin. As for the microstructural changes, the SiO 2 /Na 2 O ratio of 1.0 reduced pore size and porosity of the geopolymer coating and particularly increased volume percentage of pores with a size lower than 20 nm. Besides, FTIR results suggested that geopolymer prepared by the ratio of 1.0 was likely to produce more heterogeneous geopolymer due to a greater silicate structural reorganization.

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