CO2/H2 separation through poly(ionic liquid)–ionic liquid membranes: The effect of multicomponent gas mixtures, temperature and gas feed pressure

Gouveia, Andreia S. L.; Yañez, María Julia; Alves, Vítor D.; Palomar, José; Moya, Cristian; Gorri, Daniel; Tomé, Liliana C.; Marrucho, Isabel M.

doi:10.1016/j.seppur.2020.118113

Cited by 39 publications

(13 citation statements)

References 48 publications

(76 reference statements)

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“…It should also be noted that the P H2 also exhibited a 2–4× increase, which corresponded to a 2–3× increase in α CO2/H2 yet a decrease in α H2/N2. It should be highlighted that despite the small relative size of H 2 , these composites (like other PILs) all show selectivity for polar gases over non-polar, including P CO2 > P H2 , due to interactions with CO 2 and the membrane materials [ 42 ]. This relationship is significantly affected by the fillers or crosslinkers, as a clear shift toward the upper bound (increased P CO2 and P CO2/H2 ) was observed when comparing these composites ( Figure 7 c).…”

Section: Resultsmentioning

confidence: 99%

Design and Gas Separation Performance of Imidazolium Poly(ILs) Containing Multivalent Imidazolium Fillers and Crosslinking Agents

et al. 2021

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This work introduces a series of vinyl-imidazolium-based polyelectrolyte composites, which were structurally modified via impregnation with multivalent imidazolium-benzene ionic liquids (ILs) or crosslinked with novel cationic crosslinkers which possess internal imidazolium cations and vinylimidazolium cations at the periphery. A set of eight [C4vim][Tf2N]-based membranes were prepared via UV-initiated free radical polymerization, including four composites containing di-, tri-, tetra-, and hexa-imidazolium benzene ILs and four crosslinked derivatives which utilized tri- and tetra- vinylimidazolium benzene crosslinking agents. Structural and functional characterizations were performed, and pure gas permeation data were collected to better understand the effects of “free” ILs dispersed in the polymeric matrix versus integrated ionic crosslinks on the transport behaviors of these thin films. These imidazolium PIL:IL composites exhibited moderately high CO2 permeabilities (~20–40 Barrer), a 4–7× increase relative to corresponding neat PIL, with excellent selectivities against N2 or CH4. The addition of imidazolium-benzene fillers with increased imidazolium content were shown to correspondingly enhance CO2 solubility (di- < tri- < tetra- < hexa-), with the [C4vim][Tf2N]: [Hexa(Im+)Benz ][Tf2N] composite showing the highest CO2 permeability (PCO2 = 38.4 Barrer), while maintaining modest selectivities (αCO2/CH4 = 20.2, αCO2/N2 = 23.6). Additionally, these metrics were similarly improved with the integration of more ionic content bonded to the polymeric matrix; increased PCO2 with increased wt% of the tri- and tetra-vinylimidazolium benzene crosslinking agent was observed. This study demonstrates the intriguing interactions and effects of ionic additives or crosslinkers within a PIL matrix, revealing the potential for the tuning of the properties and transport behaviors of ionic polymers using ionic liquid-inspired small molecules.

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Section: Resultsmentioning

confidence: 99%

Design and Gas Separation Performance of Imidazolium Poly(ILs) Containing Multivalent Imidazolium Fillers and Crosslinking Agents

et al. 2021

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“…It is well known that temperature has a direct and visible effect in gas permeation properties through ILs [61]. The effect of temperature was also here studied for [C 2 mim][CF 3 BF 3 ] and [C 2 mim][CF 3 SO 2 C(CN) 2 ] filled SILMs.…”

Section: Temperature Effect On Permeation Propertiesmentioning

confidence: 99%

Tunning CO2 Separation Performance of Ionic Liquids through Asymmetric Anions

et al. 2022

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This work aims to explore the gas permeation performance of two newly-designed ionic liquids, [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2], in supported ionic liquid membranes (SILM) configuration, as another effort to provide an overall insight on the gas permeation performance of functionalized-ionic liquids with the [C2mim]+ cation. [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2] single gas separation performance towards CO2, N2, and CH4 at T = 293 K and T = 308 K were measured using the time-lag method. Assessing the CO2 permeation results, [C2mim][CF3BF3] showed an undermined value of 710 Barrer at 293.15 K and 1 bar of feed pressure when compared to [C2mim][BF4], whereas for the [C2mim][CF3SO2C(CN)2] IL an unexpected CO2 permeability of 1095 Barrer was attained at the same experimental conditions, overcoming the results for the remaining ILs used for comparison. The prepared membranes exhibited diverse permselectivities, varying from 16.9 to 22.2 for CO2/CH4 and 37.0 to 44.4 for CO2/N2 gas pairs. The thermophysical properties of the [C2mim][CF3BF3] and [C2mim][CF3SO2C(CN)2] ILs were also determined in the range of T = 293.15 K up to T = 353.15 K at atmospheric pressure and compared with those for other ILs with the same cation and anion’s with similar chemical moieties.

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“…Further studies involve the CO 2 separation from other light gases such as CH 4 and hydrogen [ 314 ]. Especially the latter seems to be a promising application field, in view of the clean production of biohydrogen as a renewable energy source, where the high solubility-selectivity of the ionic liquids favors the permeation of CO 2 over H 2 [ 142 , 315 ] and guarantees effective CO 2 removal from H 2 in multicomponent mixtures [ 316 ].…”

Section: Pil/il Blendsmentioning

confidence: 99%

A Review on Ionic Liquid Gas Separation Membranes

et al. 2021

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Ionic liquids have attracted the attention of the industry and research community as versatile solvents with unique properties, such as ionic conductivity, low volatility, high solubility of gases and vapors, thermal stability, and the possibility to combine anions and cations to yield an almost endless list of different structures. These features open perspectives for numerous applications, such as the reaction medium for chemical synthesis, electrolytes for batteries, solvent for gas sorption processes, and also membranes for gas separation. In the search for better-performing membrane materials and membranes for gas and vapor separation, ionic liquids have been investigated extensively in the last decade and a half. This review gives a complete overview of the main developments in the field of ionic liquid membranes since their first introduction. It covers all different materials, membrane types, their preparation, pure and mixed gas transport properties, and examples of potential gas separation applications. Special systems will also be discussed, including facilitated transport membranes and mixed matrix membranes. The main strengths and weaknesses of the different membrane types will be discussed, subdividing them into supported ionic liquid membranes (SILMs), poly(ionic liquids) or polymerized ionic liquids (PILs), polymer/ionic liquid blends (physically or chemically cross-linked ‘ion-gels’), and PIL/IL blends. Since membrane processes are advancing as an energy-efficient alternative to traditional separation processes, having shown promising results for complex new separation challenges like carbon capture as well, they may be the key to developing a more sustainable future society. In this light, this review presents the state-of-the-art of ionic liquid membranes, to analyze their potential in the gas separation processes of the future.

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CO2/H2 separation through poly(ionic liquid)–ionic liquid membranes: The effect of multicomponent gas mixtures, temperature and gas feed pressure

Cited by 39 publications

References 48 publications

Design and Gas Separation Performance of Imidazolium Poly(ILs) Containing Multivalent Imidazolium Fillers and Crosslinking Agents

Design and Gas Separation Performance of Imidazolium Poly(ILs) Containing Multivalent Imidazolium Fillers and Crosslinking Agents

Tunning CO2 Separation Performance of Ionic Liquids through Asymmetric Anions

A Review on Ionic Liquid Gas Separation Membranes

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