Abstract:Angesichts ausbleibender Erfolge bei der Reduktion der CO2‐Emission im Verkehr treten zunehmend auch synthetische Kraftstoffe aus CO2 und erneuerbarer elektrischer Energie in den Fokus. Für diesen sog. Power‐to‐Liquid(PtL)‐Ansatz werden neben konventionellen Technologien für Großanlagen auch intensivierte Technologien für dezentrale Anlagen in Betracht gezogen. Der Beitrag gibt einen Überblick über den Entwicklungsstand und die Perspektiven kompakter Anlagen für dezentrale PtL‐Verfahren auf Basis der Fischer‐T… Show more
“…An extensive simulation model for a PtL process was developed by König et al [13] with Aspen Plus ® providing conclusions regarding the process internal correlations and overall efficiencies. Studies concerning the decentralization of FT-based fuel production were performed by Kirsch et al [14] providing insights on the current state of technology development by the Institute for Micro Process Engineering of Karlsruhe Institute of Technology and the INERATEC GmbH (Karlsruhe, Germany). The work presented here is an extension of a conference paper [15].…”
Section: Related Studiesmentioning
confidence: 99%
“…Although still in the development stage and, therefore, not considered in the process outlined in this paper, the integration of hydrocracking in the FT reactor may, in the future, offer a further opportunity to reduce the plant complexity and enhance the process efficiency [14].…”
Section: Hydrocrackingmentioning
confidence: 99%
“…with m mol as the molar mass (g/mol) where-to account for the methane deviation-all r i,n for n > 1 are multiplied with the FT methane reaction rate according (14), and r i,n is substituted for i = paraffin and n = 1 (15):…”
Synthetic fuels play an important role in the defossilization of future aviation transport. To reduce the ecological impact of remote airports due to the long-range transportation of kerosene, decentralized on-site production of synthetic paraffinic kerosene is applicable, preferably as a near-drop-in fuel or, alternatively, as a blend. One possible solution for such a production of synthetic kerosene is the power-to-liquid process. We describe the basic development of a simplified plant layout addressing the specific challenges of decentralized kerosene production that differs from most of the current approaches for infrastructural well-connected regions. The decisive influence of the Fischer–Tropsch synthesis on the power-to-liquid (PtL) process is shown by means of a steady-state reactor model, which was developed in Python and serves as a basis for the further development of a modular environment able to represent entire process chains. The reactor model is based on reaction kinetics according to the current literature. The effects of adjustments of the main operation parameters on the reactor behavior were evaluated, and the impacts on the up- and downstream processes are described. The results prove the governing influence of the Fischer–Tropsch reactor on the PtL process and show its flexibility regarding the desired product fraction output, which makes it an appropriate solution for decentralized kerosene production.
“…An extensive simulation model for a PtL process was developed by König et al [13] with Aspen Plus ® providing conclusions regarding the process internal correlations and overall efficiencies. Studies concerning the decentralization of FT-based fuel production were performed by Kirsch et al [14] providing insights on the current state of technology development by the Institute for Micro Process Engineering of Karlsruhe Institute of Technology and the INERATEC GmbH (Karlsruhe, Germany). The work presented here is an extension of a conference paper [15].…”
Section: Related Studiesmentioning
confidence: 99%
“…Although still in the development stage and, therefore, not considered in the process outlined in this paper, the integration of hydrocracking in the FT reactor may, in the future, offer a further opportunity to reduce the plant complexity and enhance the process efficiency [14].…”
Section: Hydrocrackingmentioning
confidence: 99%
“…with m mol as the molar mass (g/mol) where-to account for the methane deviation-all r i,n for n > 1 are multiplied with the FT methane reaction rate according (14), and r i,n is substituted for i = paraffin and n = 1 (15):…”
Synthetic fuels play an important role in the defossilization of future aviation transport. To reduce the ecological impact of remote airports due to the long-range transportation of kerosene, decentralized on-site production of synthetic paraffinic kerosene is applicable, preferably as a near-drop-in fuel or, alternatively, as a blend. One possible solution for such a production of synthetic kerosene is the power-to-liquid process. We describe the basic development of a simplified plant layout addressing the specific challenges of decentralized kerosene production that differs from most of the current approaches for infrastructural well-connected regions. The decisive influence of the Fischer–Tropsch synthesis on the power-to-liquid (PtL) process is shown by means of a steady-state reactor model, which was developed in Python and serves as a basis for the further development of a modular environment able to represent entire process chains. The reactor model is based on reaction kinetics according to the current literature. The effects of adjustments of the main operation parameters on the reactor behavior were evaluated, and the impacts on the up- and downstream processes are described. The results prove the governing influence of the Fischer–Tropsch reactor on the PtL process and show its flexibility regarding the desired product fraction output, which makes it an appropriate solution for decentralized kerosene production.
“…An extensive simulation model for a PtL process was developed by König et al [13] with Aspen Plus® providing conclusions regarding the process internal correlations and overall efficiencies. Studies concerning the decentralization of FT-based fuel production are carried out by Kirsch et al [14] providing insights on the current state of technology development by the Institute for Micro Process Engineering of Karlsruhe Institute of Technology and the INERATEC GmbH. The work presented here is an extension of a conference paper [15].…”
Synthetic fuels play an important role in the defossilization of future aviation transport. To reduce the ecological impact of remote airports due to long range transportation of kerosene, a decentralized on-site-production of synthetic paraffinic kerosene is applicable, preferably as near-drop-in fuel or alternatively as blend. One possible solution for such a production of synthetic kerosene is the Power-to-Liquid process. The basic development of a simplified plant layout addressing the specific challenges of a decentralized kerosene production which differ from most current approaches for infrastructural well-connected regions is described. The decisive influence of the Fischer-Tropsch synthesis on the PtL process is shown by means of a steady-state reactor model which was developed in Python and serves as basis for further development of a modular environment able to represent entire process chains. The reactor model is based on reaction kinetics according current literature. The effects of adjustments of the main operation parameters on the reactor behavior are evaluated and the impacts on up- and downstream processes are described. The results prove the governing influence of the Fischer-Tropsch reactor on the PtL process and show its flexibility regarding the desired product fraction output, which makes it an appropriate solution for a decentralized kerosene production.
“…Loewert et al 27 investigate microstructured reactor concepts for the decentralized production of Fischer‐Tropsch fuels from renewable hydrogen and CO 2 , which are in addition characterized by good scalability 28. In experimental studies, the authors were able to couple the operation of the reactor with the profile of a photovoltaics plant directly.…”
Section: Classification Of Solutions To Enhance Flexibilitymentioning
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. Flexibility receives increased interest in chemical engineering and is discussed as one measure to deal with upcoming challenges for the chemical industry. In this paper, different types of flexibility are presented, and flexibility needs are illustrated. The focus is on the evaluation and classification of available solutions to enhance flexibility. Solutions and future challenges across all length scales of chemical engineering are discussed: from tailored catalyst properties to decoupling of processes by means of storage.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.