“…The gas properties of hydrogen, trichlorosilane, hydrogen chloride and their gas mixture, such as viscosity, thermal conductivity and heat capacity, were taken from the literature [25,26]. The properties of the mixed gas were estimated theoretically [27].…”
Silicon surface etching and its dominant rate process are studied using hydrogen chloride gas in a wide concentration range of 1 -100% in ambient hydrogen at atmospheric pressure in a temperature range of 1023 -1423 K, linked with the numerical calculation accounting for the transport phenomena and the surface chemical reaction in the entire reactor. The etch rate, the gaseous products and the surface morphology are experimentally evaluated. The dominant rate equation accounting for the first-order successive reactions at silicon surface by hydrogen chloride gas is shown to be valid. The activation energy of the dominant surface process is evaluated to be 1.5 Â 10 5 J mol À 1 . The silicon deposition by the gaseous by-product, trichlorosilane, is shown to have a negligible influence on the silicon etch rate. D
“…The gas properties of hydrogen, trichlorosilane, hydrogen chloride and their gas mixture, such as viscosity, thermal conductivity and heat capacity, were taken from the literature [25,26]. The properties of the mixed gas were estimated theoretically [27].…”
Silicon surface etching and its dominant rate process are studied using hydrogen chloride gas in a wide concentration range of 1 -100% in ambient hydrogen at atmospheric pressure in a temperature range of 1023 -1423 K, linked with the numerical calculation accounting for the transport phenomena and the surface chemical reaction in the entire reactor. The etch rate, the gaseous products and the surface morphology are experimentally evaluated. The dominant rate equation accounting for the first-order successive reactions at silicon surface by hydrogen chloride gas is shown to be valid. The activation energy of the dominant surface process is evaluated to be 1.5 Â 10 5 J mol À 1 . The silicon deposition by the gaseous by-product, trichlorosilane, is shown to have a negligible influence on the silicon etch rate. D
“…Most of these studies addressed classical reactor configurations (see Fig. 4), such as horizontal rectangular duct reactors [14,[76][77][78][79][80][81][82], vertical impinging jet and rotating disk reactors [22,[83][84][85][86][87][88], pancake reactors [89,90], barrel reactors [91][92][93], planetary reactors [94][95][96], hot-wall multi-wafer LPCVD reactors [74,[97][98][99]. Many studies were devoted to low pressure single wafer reactors of the stagnation flow type [21,28,[100][101][102].…”
Section: Cvd Simulation Models: a Literature Reviewmentioning
“…The rotating disk geometry has the important property that in certain operating regimes [44] the species and temperature gradients normal to the disk are equal everywhere on the disk. The equations describing the complex three-dimensional spiral fluid motion can be solved by a separation-ofvariables transformation [45,46] that reduces the equations to a system of ordinary differential equations.…”
Chemical reactions in the gas-phase and on surfaces are important in the deposition and etching of materials for microelectronic applications. A general software framework for describing homogeneous and heterogeneous reaction kinetics utilizing the Chemkin suite of codes is presented. Experimental, theoretical and modeling approaches to developing chemical reaction mechanisms are discussed. A number of TCAD application modules for simulating the chemically reacting flow in deposition and etching reactors have been developed and are also described.
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