Nematic liquid crystals of achiral
molecules or racemic mixtures
of chiral ones form flat films when suspended in submillimeter size
grids and submerged under water. Recently, it has been shown (Popov
et al., 2017) that films of nematic liquid crystals doped with chiral
molecules adopt biconvex lens shapes underwater. The curved shape
together with degenerate planar anchoring leads to a radial variation
of the optical axis along the plane of the film, providing a Pancharatnam–Berry-type
phase lens that modifies geometric optical imaging. Here, we describe
nematic liquid crystal microlenses formed by the addition of chiral
nanoparticles. It is found that the helical twisting power of the
nanoparticles, the key factor to form the lens, is about 400 μm–1, greater than that of the strongest molecular chiral
dopants. We demonstrate imaging capabilities and measure the shape
as well as the focal length of the chiral nanoparticle-doped liquid
crystal lens. We show that measuring the shape of the lens allows
one to calculate the helical pitch of the chiral nematic liquid crystal
and thus determine the helical twisting power of the chiral ligand-capped
nanoparticles. Such measurements require the use of only nanograms
of chiral nanoparticles, which is 3 orders of magnitude less than
that required by conventional techniques. Since NPs are sensitive
to external stimuli such as light and electric and magnetic fields,
the use of chiral NPs may allow the achievement of tunable optical
properties for such microlens arrays.