“…This may affect the kinetic modeling of multiple contaminants such as PAHs, over the entire contact time. That is why some previous researchers reported a two phase desorption kinetics of desorption [37,40]. The majority of Pb probably exist in available forms (exchangeable and carbonate fraction) [41].…”
This work aims to investigate the competitive time-dependent desorption rate of heavy metals (lead, zinc, nickel) coexisting with phenanthrene from natural high buffering soil. Two non-ionic surfactants (Tween 80 and Brij 35) combined with disodium ethylene diamine tetraacetate salt (Na2-EDTA) were utilized as the reagents. The contaminants' time-dependent desorption data was fitted with five kinetic models including parabolic diffusion, Elovich, fractional power function, pseudo-first and-secondorder equations. The best removal of contaminants obtained by the mixture of Tween 80/EDTA; desorbing 93% of lead (Pb). The competitive desorption of nickel (Ni) and zinc (Zn) is affected by the stability of Metal-EDTA complexes. Moreover, phenanthrene removal in the soil studied was slow and laborious. The desorption kinetics are well described by parabolic diffusion (for phenanthrene) and pseudo-second-order (for heavy metals of interest). In the soil-surfactant-water system, soil structure changes were negligible; however, Tween 80 influenced the development of crystal faces of CaCO3 during the process.
“…This may affect the kinetic modeling of multiple contaminants such as PAHs, over the entire contact time. That is why some previous researchers reported a two phase desorption kinetics of desorption [37,40]. The majority of Pb probably exist in available forms (exchangeable and carbonate fraction) [41].…”
This work aims to investigate the competitive time-dependent desorption rate of heavy metals (lead, zinc, nickel) coexisting with phenanthrene from natural high buffering soil. Two non-ionic surfactants (Tween 80 and Brij 35) combined with disodium ethylene diamine tetraacetate salt (Na2-EDTA) were utilized as the reagents. The contaminants' time-dependent desorption data was fitted with five kinetic models including parabolic diffusion, Elovich, fractional power function, pseudo-first and-secondorder equations. The best removal of contaminants obtained by the mixture of Tween 80/EDTA; desorbing 93% of lead (Pb). The competitive desorption of nickel (Ni) and zinc (Zn) is affected by the stability of Metal-EDTA complexes. Moreover, phenanthrene removal in the soil studied was slow and laborious. The desorption kinetics are well described by parabolic diffusion (for phenanthrene) and pseudo-second-order (for heavy metals of interest). In the soil-surfactant-water system, soil structure changes were negligible; however, Tween 80 influenced the development of crystal faces of CaCO3 during the process.
“…Moreover, pertaining to the clay mineral composition, montmorillonite had stronger adsorption ability to nonionic surfactant such as Triton X-100 (TX100) than kaolinite (S anchez-Martín et al, 2008). We observed that soil samples collected in Guangzhou showed low adsorption capacity towards TX100 (Wei et al, 2015), which might be due to that the main clay composition of soil in Pearl River Delta is kaolinite (Liu et al, 2012b). However, the influence of SOM on the adsorption of TX100 onto soil in Pearl River Delta remains yet to be studied.…”
“…For the remediation of contaminated soils, the application of surfactants is gaining importance [47][48][49][50][51]. Ferrocenebased surfactants have the advantage to act both as surfactants and as redox-active compounds.…”
Ferrocene and derivatives find numerous application in agriculture, both as agrochemicals and as catalysts for selective synthesis of agrochemicals. Moreover, they can be used as surfactants in soil remediation and as selective colorimetric and electrochemical chemosensors for analytes of interest in agriculture
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