Organic montmorillonite (OMMT) reinforced phenolic (PF) nanocomposites with OMMT contents of 2 and 5 wt% were fabricated by the two-step OMMT intercalation process, resulting in the further increase of interlayer spacing of OMMT from 2.07 nm to 4.27 nm. Prepared OMMT/PF composites were found to possess a mix of intercalated and agglomerated clay structures via X-ray diffraction (XRD) analysis and transmission electron microscopy (TEM). TG-DTG and DSC results revealed that the thermal stability of PF matrices was enhanced by the incorporation of OMMT. With OMMT/PF nanocomposites as hybrid matrices, fabric self-lubricating liners were prepared to evaluate their tribological properties. Effects of OMMT on friction coefficient, wear loss and wear morphology of fabric self-lubricating liner, based on OMMT/PF nanocomposites, were studied via long-term friction and wear tests. Tribological properties of liners with different OMMT contents were investigated by imitating high velocity/light load condition. The addition of OMMT appears to enhance the friction and wear properties of fabric self-lubricating liner and the preferable addition content of the OMMT is around 2 wt%.