No abstract

With the popularization of 5G communications and the internet of things, electromagnetic wave (EW) radiation pollution has aroused much concern from the public, and the search for new materials and technologies for preparing electromagnetic shielding materials still continues all around the world. However, the contradiction among high shielding performance, economic applicability, and flexibility is still not well balanced. Herein, we fabricated a novel foldable leather solid waste (LSW)/polyvinyl alcohol (PVA)/silver (Ag) paper with excellent electromagnetic interference (EMI)-shielding ability using a facile but sustainable electroless plating (ELP) method with LSW as the resource. Taking PVA as a cross-linker, debundled leather fibers (LFs) generated by solid-state shearing milling could generate a flexible LSW/PVA substrate with a high specific surface area, and eventually the deposited Ag layer served as a protective layer not only to significantly improve the mechanical and thermal robustness, but also to endow the LSW/PVA/Ag paper with good hydrophobicity, which could protect from potential moisture damage. In addition to the reflection effect of metallic Ag on EW, the hierarchical structure of collagen fibers played an important role in superior high EMI-shielding effectiveness (∼55–∼90 dB) by an absorption-dominant EMI-shielding mechanism. Furthermore, a multilayer LSW/PVA/Ag paper was also prepared with enhanced EMI-shielding effectiveness of 111.3 dB benefited by constructing multiple reflection–absorption interfaces. The high-performance, environmentally friendly, and low-cost EMI-shielding materials not only offered a new avenue toward recycling LSW in a more value-added way, but also displayed promising potential for application in flexible shielding materials or wearable clothing.

Triboelectric polymer with high charge density is the foundation to promote the wide range of applications of triboelectric nanogenerators. This work develops a method to produce triboelectric polymer based on repeated rheological forging. The fluorinated ethylene propylene film fabricated by repeated forging method not only has excellent mechanical properties and good transmittance, but also can maintain an ultrahigh tribo-charge density. Based on the film with a thickness of 30 μm, the output charge density from contact-separation nanogenerator reaches 352 μC·m−2. Then, the same film is applied for the nanogenerator with air-breakdown mode and a charge density of 510 μC·m−2 is further achieved. The repeated forging method can effectively regulate the composition of surface functional groups, the crystallinity, and the dielectric constants of the fluorinated ethylene propylene, leading to the superior capability of triboelectrification. Finally, we summarize the key parameters for elevating the electrification performance on the basis of molecular structure and related fabrication crafts, which can guide the further development of triboelectric polymers.