ChemInform Abstract: THERMAL TRANSFORMATION OF ADDUCTS OF PHOSPHORUS PENTACHLORIDE WITH ALKYL ALLYL ETHERS

Kormachev, V. V.; Mitrasov, Yu. N.; Kukhtin, V. A.

doi:10.1002/chin.197944257

Chemischer Informationsdienst

1979

DOI: 10.1002/chin.197944257

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ChemInform Abstract: THERMAL TRANSFORMATION OF ADDUCTS OF PHOSPHORUS PENTACHLORIDE WITH ALKYL ALLYL ETHERS

V. V. Kormachev¹,

Yu. N. Mitrasov²,

V. A. Kukhtin³

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2013

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“…It is known that one of the available mild phosphorylating agents is phosphorus pentachloride possessing electrophilic character [1]. Therefore, its reaction with such spiranes may occur through an opening of a three-or four-membered rings to produce new types of phosphorylated cyclic hydrocarbons.…”

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Reaction of spiro[2.2]pentane with phosphorus pentachloride

2013

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Due to the high strain energy spiranes containing small cycles are interesting objects for phosphorylation with phosphorus compounds of various coordination. It is known that one of the available mild phosphorylating agents is phosphorus pentachloride possessing electrophilic character [1]. Therefore, its reaction with such spiranes may occur through an opening of a three-or four-membered rings to produce new types of phosphorylated cyclic hydrocarbons.We showed that the interaction of spiro[2.2]pentane I with phosphorus pentachloride under standard conditions [2] (benzene, 0-20°C, quenching reagent acetone) resulted in 1-chlorocyclobutyl-methylphosphonic acid dichloride II.

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Reaction of spiro[2.2]pentane with phosphorus pentachloride

2013

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ChemInform Abstract: THERMAL TRANSFORMATION OF ADDUCTS OF PHOSPHORUS PENTACHLORIDE WITH ALKYL ALLYL ETHERS

Cited by 1 publication

References 0 publications

Reaction of spiro[2.2]pentane with phosphorus pentachloride

Reaction of spiro[2.2]pentane with phosphorus pentachloride

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