ChemInform Abstract: THERMAL ADDITIONS OF DIMETHYL ACETYLENEDICARBOXYLATE TO CYCLIC THIOENOL ETHER‐1‐OXIDES WITH RING EXPANSION

Gollnick, Klaus; Fries, Siegfried

doi:10.1002/chin.198104104

Chemischer Informationsdienst

1981

DOI: 10.1002/chin.198104104

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ChemInform Abstract: THERMAL ADDITIONS OF DIMETHYL ACETYLENEDICARBOXYLATE TO CYCLIC THIOENOL ETHER‐1‐OXIDES WITH RING EXPANSION

Klaus Gollnick¹,

Siegfried Fries²

Abstract: Dihydrothiophenoxid (Ia) sowie die Dihydrothiopyranoxide (Ib) und (Ic) reagieren mit Acetylendicarbonsäureester beim Kochen unter Rückfluß in Toluol in einer postulierten [2 + 3 ]‐Cycloaddition zu den Dihydrothiepin‐ bzw. Dihydrothiocin‐Oxiden (II).

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ChemInform Abstract: THERMAL ADDITIONS OF DIMETHYL ACETYLENEDICARBOXYLATE TO CYCLIC THIOENOL ETHER‐1‐OXIDES WITH RING EXPANSION

Abstract: Dihydrothiophenoxid (Ia) sowie die Dihydrothiopyranoxide (Ib) und (Ic) reagieren mit Acetylendicarbonsäureester beim Kochen unter Rückfluß in Toluol in einer postulierten [2 + 3 ]‐Cycloaddition zu den Dihydrothiepin‐ bzw. Dihydrothiocin‐Oxiden (II).

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