ChemInform Abstract: The Development of Phosphinoamine—Pd(II)—Imidazole Complexes: Implications in Room‐Temperature Suzuki—Miyaura Cross‐Coupling Reaction.

Borah, Geetika; Boruah, Devajani; Sarmah, Gayatri; Bharadwaj, Saitanya K.; Bora, Utpal

doi:10.1002/chin.201419084

Cited by 1 publication

(1 citation statement)

References 1 publication

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“…In the case of palladium nanoparticles incorporated onto cellulose paper and wool only [5][6] recycles are feasible, 16,17 whilst incorporation of palladium(II) species within a polymer film as an alternative to palladium nanoparticles suffers from high levels of metal leaching contributing towards homogeneous (rather than heterogeneous) catalysis. 18,19,20,21 Although imidazole based ligands for palladium catalysis are extensively used in homogeneous Mizoroki-Heck 22,25 and Suzuki-Miyaura 23,24,25,26 coupling reactions, their application on solid surfaces to anchor palladium catalysts has not been previously reported. In this article, we describe the anchoring of palladium catalyst sites through surface imidazole groups formed by pulsed plasma deposition of poly(1-allylimidazole) onto a cheap non-woven polypropylene support, Scheme 1.…”

Section: Introductionmentioning

confidence: 99%

Recyclable palladium catalyst cloths for carbon-carbon coupling reactions

Wilson

Kore

Fraser

et al. 2017

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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(2017) 'Recyclable palladium catalyst cloths for carbon-carbon coupling reactions.', Colloids and surfaces A : physiochemical and engineering aspects., 520 . pp. 788-795. Further information on publisher's website: Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. product yields (54%, 82%, and 99% respectively) and selectivities (99%, 93%, and greater than 99% respectively) have been measured. These palladium catalyst cloths show low levels of metal leaching and can be recycled multiple times.

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