ChemInform Abstract: Synthesis of N‐Phosphorylsulfamates (as Pyrophosphate and Carbamylphosphate Analogues) Through an Imidate—Amidate Rearrangement.

Boudjabi, Sihem; Dewynter, Georges; Montéro, Jean-Louis

doi:10.1002/chin.200034164

Cited by 4 publications

(4 citation statements)

References 5 publications

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“…Interpretation of the IR spectra of the compounds based on H L is more complicated because of the proximity of absorption bands of ν(SO 2 ) as , ν(SO 2 ) s , and ν(PO) vibrations. On the basis of the principles listed in ref and the correlation between the synthesized complexes and related compounds with CAPh , and SAPh, ,− assignment of the absorption bands in the IR spectra of the obtained complexes was done as discussed below.…”

Section: Resultsmentioning

confidence: 99%

Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand

et al. 2018

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A series of new anionic lanthanide(III) complexes with the general formula NEt 4 [LnL 4 ] (1-Ln; HL = dimethyl[(4-methylphenyl)sulfonyl]amidophosphate; Ln = La, Nd, Eu), were synthesized and characterized by IR, UV− vis, and NMR spectroscopies, the differential scanning calorimetry method, thermogravimetric and X-ray analysis, and photoluminescence measurements. Single-crystal structures of NEt 4 [EuL 4 ] (1-Eu) were determined at 293 and 100 K and evidenced the single-crystal-to-single-crystal phase transition. Both phases are in the monoclinic crystal system in centrosymmetric groups of the same Laue class. The room temperature structure is in C2/c (No. 15), while lowtemperature structure is in the P2 1 /c (No. 14) space groups. The coordination environment geometry around the central europium(III) ion is a distorted square antiprism in both polymorphs, while the peripheral methoxy and tolyl groups show different orientations. This phenomenon indicates the occurrence of a thermally driven second-order phase transition during the cooling−heating process. The europium(III) complex exhibits an unusual emission spectrum, clearly dominated by the 5 D 0 − 7 F 4 bands, and an emission decay time equaling 3.5 ms, being among the highest values known for europium coordination compounds.

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Section: Resultsmentioning

confidence: 99%

Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand

et al. 2018

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“…The complex is light sensitive. IR for (AgL) n (nujol mull, ν cm ) [9,10]. X-ray diffraction study was carried out for (AgL) n .…”

Section: Resultsmentioning

confidence: 99%

Laser desorption/ionization (LDI MS) of polymeric silver(I) coordination compound based on N-[bis(diethylamino)phosphoryl]-benzenesulfonamide

Shatrava¹,

Severinovskaya²,

Оvchynnikov³

et al. 2016

Him. Fiz. Tehnol. Poverhni

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“…An example of N-phosphoryl sulfamate was synthesized only recently, in the reaction of n-octylsulfamate with trialkyl phosphite in the presence of diisopropylazodicarboxylate and subsequent isomerization of the formed phosphazene with DABCO [29].…”

Section: Methodsmentioning

confidence: 99%

Oxidation of diethyl N‐sulfinylphos‐phoramidates

Mielniczak

Łopusiński

2008

Heteroatom Chemistry

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ChemInform Abstract: Synthesis of N‐Phosphorylsulfamates (as Pyrophosphate and Carbamylphosphate Analogues) Through an Imidate—Amidate Rearrangement.

Cited by 4 publications

References 5 publications

Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand

Synthesis and Characterization of Anionic Lanthanide(III) Complexes with a Bidentate Sulfonylamidophosphate (SAPh) Ligand

Laser desorption/ionization (LDI MS) of polymeric silver(I) coordination compound based on N-[bis(diethylamino)phosphoryl]-benzenesulfonamide

Oxidation of diethyl N‐sulfinylphos‐phoramidates

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