ChemInform Abstract: SYNTH. VON DERIVATEN DES 2‐HYDRAZONO‐THIAZOLIDONS‐(4) AUS THIOSEMICARBAZID‐DERIVATEN

Svetkin, Yu. V.; Minlibaeva, A. N.; Mansurova, A. G.

doi:10.1002/chin.197248320

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B 4-thiazolidinones1

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1981

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“…Mixed anhydride (67), prepared by passing ketene into chloroacetic acid, reacts with substituted and unsubstituted thioureas in chloroform at 60 °C to give various 2-imino-4-thiazolidinoneslu'112 (68). Various 3-substituted-2-thiono-4-thiazolidinones (69) can be conveniently prepared by the reaction of substituted isothiocyanates with a-mercaptoacetic acid or its ester followed by acid cyclization of the resulting (thiocarbamoyl)mercaptoacetic acids and acetates.113 amount of alcoholate to give 4-thiazolidinones147,148 (74).…”

Section: B 4-thiazolidinonesmentioning

confidence: 99%