ChemInform Abstract: REACTION OF 2‐METHYLCERAMIDONINE WITH COMPOUNDS CONTAINING AN ACTIVE METHYLENE GROUP

Ektova, L. V.; Shishkina, R. P.; Fokin, E. P.

doi:10.1002/chin.197737224

Cited by 1 publication

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“…More recently, ceramidonines (e.g., 127.11 and 127.13 ) were obtained by direct benzyne cycloadditions to 1-aminoanthraquinone 127.9 . The requisite benzyne intermediates were generated from o -(trimethylsilyl)phenyl triflate 127.10 by Rogness and Larock and from 5-arylthianthrenium perchlorates (e.g., 127.12 ) by Kim et al The reactivity of ceramidonines in electrophilic and nucleophilic substitutions was investigated, with a range of reagents being explored, such as amines, − active methylene compounds, arylsulfinic acids, alkoxides, potassium cyanide, and thiophenols . Functionalized ceramidonines containing s -triazine and sulfonamide groups were developed for use in dyeing.…”

Section: Phenalenoidsmentioning

confidence: 99%

Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications

et al. 2016

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Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic nanographenes) are a highly versatile class of organic materials, applicable as functional chromophores and organic semiconductors. In this Review, we discuss the rich chemistry of large heteroaromatics, focusing on their synthesis, electronic properties, and applications in materials science. This Review summarizes the historical development and current state of the art in this rapidly expanding field of research, which has become one of the key exploration areas of modern heterocyclic chemistry.

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