ChemInform Abstract: Raman Spectra of Anion‐ and Cation‐Substituted Substituted Ternary Oxides of Molybdenum and Tungsten with the Pyrochlore or Hexagonal Tungsten Bronze Structures. Single Crystal Structure Analysis of CsZnMoO3F3 (I), Rb0.3Nb0.3W0.7O3 (II), and Rb0.3Ga0.1W0.9O3 (III).

Abstract

The Raman spectra of A(BxW1‐x)O3 (A: K, Rb, Cs; B: Mg, Al, Ga, Ti, V, Nb, Ta) with defect pyrochlore or hexagonal tungsten bronze (HTB) structure and of Cs(BMO3F3) (M: Mo, W; B: Ni, Cu, Zn) and AM2O5F (A: Rb, Cs; M: Nb, Ta) with defect pyrochlore structure are detected (synthesis conditions are given in a table).