2009
DOI: 10.1002/chin.200931060
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ChemInform Abstract: Poly(N,N′‐dibromo‐N‐ethyl‐benzene‐1,3‐disulfonamide), N,N,N′,N′‐Tetrabromobenzene‐1,3‐disulfonamide and Novel Poly(N,N′‐dibromo‐N‐phenylbenzene‐1,3‐disulfonamide) as Powerful Reagents for Benzylic Bromination.

Abstract: benzene-1,3-disulfonamide and Novel Poly(N,N'-dibromo-N-phenylbenzene--1,3-disulfonamide) as Powerful Reagents for Benzylic Bromination. -The title reagents can be used for the synthesis of a variety of benzylic bromides from methyl arenes. Xylenes are converted to bis-bromomethyl compounds. -(GHORBANI--VAGHEI*, R.; CHEGINI, M.; VEISI, H.; KARIMI-TABAR, M.; Tetrahedron Lett.

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“…TBBDA, poly(N,N / -dibromo-N-ethyl-benzene-1,3-disulfonamide) [PBBS], and poly(N,N / -dibromo-N-phenylbenzene-1,3-disulfonamide) [PBPS] can be used for the bromination of benzylic positions in a solvent under reflux conditions in the presence of benzoyl peroxide. 1177 CCl 4 and EtOAc are the best solvents to carry out the bromination with these reagents (Scheme 411).…”
Section: Kumar Et Al Proposed a New Environmentally Benign Protocolmentioning
confidence: 99%
“…TBBDA, poly(N,N / -dibromo-N-ethyl-benzene-1,3-disulfonamide) [PBBS], and poly(N,N / -dibromo-N-phenylbenzene-1,3-disulfonamide) [PBPS] can be used for the bromination of benzylic positions in a solvent under reflux conditions in the presence of benzoyl peroxide. 1177 CCl 4 and EtOAc are the best solvents to carry out the bromination with these reagents (Scheme 411).…”
Section: Kumar Et Al Proposed a New Environmentally Benign Protocolmentioning
confidence: 99%