ChemInform Abstract: Phthalocyanines and Related Compounds. Part 28. Synthesis, Spectra and Electrochemical Studies of Monophthalocyanines of the Rare Earths.

Subbotin, N. B.; Tomilova, Larisa G.; Kostromina, N. A.; Luk'yanets, E. A.

doi:10.1002/chin.198637295

Cited by 11 publications

(15 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…The above mentioned phthalocyaninatolithium was also used for the synthesis of REE monophthalocyaninato complexes. [10] Magnesium complexes can be transmetallated in acidic media [11] and cadmium ions in porphyrin complexes can be exchanged by cobalt or zinc ions in polar solvents. [12] However, REE exchange was never reported previously.…”

Section: Resultsmentioning

confidence: 99%

Diphthalocyaninatolanthanum as a New Phthalocyaninato‐Dianion Donor for the Synthesis of Heteroleptic Triple‐Decker Rare Earth Element Crown‐Phthalocyaninato Complexes

et al. 2007

View full text Add to dashboard Cite

show abstract

Section: Resultsmentioning

confidence: 99%

Diphthalocyaninatolanthanum as a New Phthalocyaninato‐Dianion Donor for the Synthesis of Heteroleptic Triple‐Decker Rare Earth Element Crown‐Phthalocyaninato Complexes

et al. 2007

View full text Add to dashboard Cite

show abstract

“…[57] Reaction mixture was cooled and diluted with a double volume of water. A residue was filtered, washed with water and air-dried.…”

Section: Methodsmentioning

confidence: 99%

Reactivity of Rare Earth Metal Porphyrins/Phthalocyanines in Acid Media

Ломова¹,

Klyueva²,

Oskar³

2015

MHC

View full text Add to dashboard Cite

“…Complexes (X)LnPc were prepared from Li 2 Pc and the corresponding Ln salt by procedure similar to that described in [21]. Li 2 Pc and LnX 3 ⋅ 6H 2 O ((AcO) 3 Sm ⋅ 2H 2 O) in 1 : 2 molar ratio were introduced into DMSO, the mixture was heated to reflux, thermo stated at boiling temperature for 15-20 min, and cooled.…”

Section: Methodsmentioning

confidence: 99%

Mutual effects of equatorial and axial ligands on the stability of praseodymium(III) and samarium(III) phthalocyanine complexes

Ломова

2015

Russ. J. Inorg. Chem.

View full text Add to dashboard Cite

The nature of axial ligand in lanthanide(III) phthalocyanine complexes markedly affects their physicochemical properties. The role of axially coordinated anion in the stability of coordination sphere was determined by the example of praseodymium(III) and samarium(III) phthalocyanine complexes (X)LnPc (X = Cl -, Br -, AcO -). The synthesis and the results of dissociation kinetics study of the complexes under the action of AcOH in ethanol solution were presented. Stability parameters for the complexes, kinetic equa tions, and activation parameters for the dissociation of coordination centers were determined. Effect of the axial ligand on the strength of macrocycle binding and the stoichiometric mechanism of complex dissociation reaction was considered. The state of axial bond in the complexes was shown to determine the value of reac tion order toward acid (1 or 2) and the nature of rate limiting step of the reaction: with participation of mol ecule or ionized in the axial direction complex.

show abstract

ChemInform Abstract: Phthalocyanines and Related Compounds. Part 28. Synthesis, Spectra and Electrochemical Studies of Monophthalocyanines of the Rare Earths.

Cited by 11 publications

References 0 publications

Diphthalocyaninatolanthanum as a New Phthalocyaninato‐Dianion Donor for the Synthesis of Heteroleptic Triple‐Decker Rare Earth Element Crown‐Phthalocyaninato Complexes

Diphthalocyaninatolanthanum as a New Phthalocyaninato‐Dianion Donor for the Synthesis of Heteroleptic Triple‐Decker Rare Earth Element Crown‐Phthalocyaninato Complexes

Reactivity of Rare Earth Metal Porphyrins/Phthalocyanines in Acid Media

Mutual effects of equatorial and axial ligands on the stability of praseodymium(III) and samarium(III) phthalocyanine complexes

Contact Info

Product

Resources

About