ChemInform Abstract: OXIDATION METHYLSUBSTITUIERTER AROMATEN MIT ALKALIMETALLPERSULFATEN

Andreeva, L. K.; Birger, E. A.; Kheifits, L. A.

doi:10.1002/chin.197537121

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2000

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“…1, [9][10][11] Some radical characteristics were also observed in our reaction system. The effect of a radical scavenger on the reaction is also shown in Fig.…”

Section: Resultsmentioning

confidence: 58%

Cu(OAc)2-catalyzed partial oxidation of methane to methyl trifluoroacetate in the liquid phase

Yin

Piao

Kitamura

et al. 2000

Appl. Organometal. Chem.

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Simple transition-metal salts were investigated as the catalysts for the partial oxidation of methane. In trifluoroacetic acid (TFA), methane could be efficiently converted to methyl trifluoroacetate by the Cu(OAc) 2 /K 2 S 2 O 8 catalyst system. A quantitative yield (96.3%) based on methane has been obtained under the optimized conditions. A possible mechanism involving radical intermediates has been suggested for this reaction.

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“…1, [9][10][11] Some radical characteristics were also observed in our reaction system. The effect of a radical scavenger on the reaction is also shown in Fig.…”

Section: Resultsmentioning

confidence: 58%

Cu(OAc)2-catalyzed partial oxidation of methane to methyl trifluoroacetate in the liquid phase

Yin

Piao

Kitamura

et al. 2000

Appl. Organometal. Chem.

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: OXIDATION METHYLSUBSTITUIERTER AROMATEN MIT ALKALIMETALLPERSULFATEN

Abstract: Bei Oxidationen der Toluole (I) mit Kzsgog in wäßriger Suspension bei 60°C zu den Aldehyden (II) läßt sich das als Katalysator erforderliche AgNO3 bei gleichzeitigem Zusatz von K‐oxalat durch Cu‐salze ersetzen.

Cited by 1 publication

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Cu(OAc)2-catalyzed partial oxidation of methane to methyl trifluoroacetate in the liquid phase

Cu(OAc)2-catalyzed partial oxidation of methane to methyl trifluoroacetate in the liquid phase

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