ChemInform Abstract: Organotransition Metal Modified Carbohydrates. Part 6. Metal Modified Carbohydrates: Syntheses of Furanosylidene Complexes and Their Aza Analogues.

Abstract

Organotransition Metal Modified Carbohydrates. Part 6. Metal Modified Carbohydrates: Syntheses of Furanosylidene Complexes and Their Aza Analogues. -The novel transition metal stabilized complexes (III), (V), and (VIII) are stable at room temperature and can be handled briefly in air. As Fischer-type carbene complexes they are promising agents for the elaboration of more complex C-glycosidic structures. -(DOETZ, K. H.; HAASE, W.-C.; KLUMPE, M.; NIEGER, M.; Chem.