ChemInform Abstract: Nucleophilic Ring Opening and Closure Reactions in Saturated Heterocycles

Bobylev, V. A.; Koldobskii, S. G.; Tereshchenko, G. F.; Gidaspov, B. V.

doi:10.1002/chin.198916381

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Synthesis Of Amino Alcohols From Cage-like Bicyclic Epoxides1

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2010

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“…Aminolysis of epoxides was the subject of many theoretical studies involving quantum-chemical calculations [26][27][28][29]. The results of these studies were summarized in [12,13,30]; they confirmed the classical Parker-Isaacs mechanism with transition state 1 [23].…”

Section: Synthesis Of Amino Alcohols From Cage-like Bicyclic Epoxidessupporting

confidence: 53%

Cage-like amino alcohols. synthesis, reactions, and application

Kas’yan

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2010

Russ J Org Chem

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The review analyzes methods for the synthesis of amino alcohols containing cage-like norbornene, norbornane, and adamantane fragments. Such reactions of amino alcohols as selective functionalization of hydroxy and amino groups, as well as heterocyclizations with formation of nitrogen-and oxygen-containing heterocycles, are considered. Biological activity of cage-like amino alcohols and their derivatives and their use as ligands in catalytic asymmetric syntheses are discussed.

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