ChemInform Abstract: Halogenation of Tris(arylamino)phosphazobenzenes.

Kostina, V. G.; Rutkovskii, E. K.; Feshchenko, N. G.

doi:10.1002/chin.199251226

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Bromination Reactions 31 Bromination With Molecular Bromine1

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2016

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“…Regioselective halogenation of tris(arylamido)phosphazobenzenes with bromine was reported by Kostina et al, affording the entirely para-substituted product. 325 In the case of bromination, intermediate phosphonium bromide (p-BrC 6 H 4 ) 4 P + Br − was isolated in quantitative yield. Ransford reported the synthesis of decabromodiphenylalkane by AlCl 3 -catalyzed bromination of diphenylalkane with bromine.…”

Section: Bromination Reactions 31 Bromination With Molecular Brominementioning

confidence: 99%

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

2016

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Bromination is one of the most important transformations in organic synthesis and can be carried out using bromine and many other bromo compounds. Use of molecular bromine in organic synthesis is well-known. However, due to the hazardous nature of bromine, enormous growth has been witnessed in the past several decades for the development of solid bromine carriers. This review outlines the use of bromine and different bromo-organic compounds in organic synthesis. The applications of bromine, a total of 107 bromo-organic compounds, 11 other brominating agents, and a few natural bromine sources were incorporated. The scope of these reagents for various organic transformations such as bromination, cohalogenation, oxidation, cyclization, ring-opening reactions, substitution, rearrangement, hydrolysis, catalysis, etc. has been described briefly to highlight important aspects of the bromo-organic compounds in organic synthesis.

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Section: Bromination Reactions 31 Bromination With Molecular Brominementioning

confidence: 99%