ChemInform Abstract: ELECTROORGANIC CHEMISTRY. XXIV. REDUCTIVE CYCLIZATION OF NONCONJUGATED ACETYLENIC KETONES TO 2‐METHYLENECYCLOPENTANOLS

Shono, Tatsuya; Nishiguchi, Ikuzo; Omizu, Hiroshi

doi:10.1002/chin.197718169

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C−c Bonds Formation1

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2017

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“…Electroreductive Intramolecular Coupling of Ketones with Unsaturated Functional Groups. Electroreduction of ketones produces ketyl radicals efficiently, and hence a variety of electroreductive couplings of ketones with olefins, 36,37 alkynes, 38 and aromatic rings 39−41 have been developed. If there is a heteroatom such as a nitrogen or a sulfur atom between the unsaturated group and the carbonyl group, an intramolecular reductive couplings would lead to the formation of heteroatomcontaining cyclic compounds.…”

Section: C−c Bonds Formationmentioning

confidence: 99%

Use of Electrochemistry in the Synthesis of Heterocyclic Structures

2017

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The preparation and transformation of heterocyclic structures have always been of great interest in organic chemistry. Electrochemical technique provides a versatile and powerful approach to the assembly of various heterocyclic structures. In this review, we examine the advance in relation to the electrochemical construction of heterocyclic compounds published since 2000 via intra- and intermolecular cyclization reactions.

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Section: C−c Bonds Formationmentioning

confidence: 99%