ChemInform Abstract: ASYMMETRIC SYNTHESIS AND RETRORACEMIZATION OF AMINO ACIDS VIA COPPER(II) COMPLEXES WITH SCHIFF BASES BETWEEN CHIRAL 1‐(N,N‐DIMETHYLAMINOMETHYL)‐2‐FORMYLCYMANTRENE AND DIPEPTIDES
Abstract:Die rac. Titelverbindung (I) wird mittels Komplexbildung zu (III) bzw. (IV) (ähnliche Darstellung) und nachfolgende Zers. in ihre Enantiomeren(R)‐(I) und (S)‐(I) gespalten (Konfigurationsbestimmung von (S)‐(I) durch Röntgenstrukturanalyse (P21212l; Z=4)).
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