The rare gas quenching rate constants of the metastable species,
O2
was measured using an induced
fluorescence technique that utilizes an incoherent broadband light
source and an integrating sphere to maximize
excitation efficiency and fluorescence light collection. The
measured rate constants at 295 K were the following
(in units of 10-20 cm3
molecule-1 s-1): He, 430 ± 13; Ne, 26
± 5; Ar, 9 ± 5; Kr, 32 ± 3; Xe, 67 ± 5. These
values are of much lower magnitude than previous results indicate.
However, except for that of helium,
these rate constants should be regarded as upper limits, given that
water vapor and hydrogen (both highly
efficient quenchers) are ubiquitous contaminants of gas samples.
The quenching rate constant with ground-state oxygen derived from these experiments, (4.25 ± 0.52) ×
10-17 cm3 molecule s-1, is in
excellent agreement
with previous results.