Charge
density wave (CDW) as a novel effect in two-dimensional transition
metal dichalcogenides (TMDs) has obtained a rapid rise of interest
for its physical nature and potential applications in oscillators
and memory devices. Here, we report var der Waals epitaxial growth
of centimeter-scale 1T-VTe2 thin films on mica by molecular
beam epitaxy. The VTe2 thin films showed sudden resistance
change at temperatures of 240 and 135 K, corresponding to two CDW
phase transitions driven by temperature. Moreover, the phase transitions
can be driven by an electric field due to local Joule heating, and
the corresponding resistance states are nonvolatile and controllable,
which could be applied to the memory device where the logic states
can be switched by an electric field. The multistage CDW phase transitions
in the VTe2 thin films could be contributed to electron–phonon
coupling in the two-dimensional VTe2, which is supported
by twice pronounced Raman blue shifts of the vibration modes associated
with in-plane phonons at CDW phase transition temperature. The results
open up a new platform for understanding the microscopic physical
essence and electrical control of CDW phases of TMDs, expanding the
functionalities of these materials for memory applications.