2010
DOI: 10.1016/j.jelechem.2010.02.006
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Characterization of lapachol in artificial organic-film membrane: Application for the trans-membrane transport of Mg2+

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Cited by 6 publications
(9 citation statements)
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“…The inset of Figure 4 shows the variation of the scan rate-normalised cathodic peak current, , /V versus V, for cathodic peak II. The ratio /V for cathodic peak decreases severely with an increasing scan rate, indicating a CE mechanism in which the electrode reaction is gated by a slow preceding chemical step [15,26]. These results suggest that the two systems are not similar.…”
Section: Resultsmentioning
confidence: 90%
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“…The inset of Figure 4 shows the variation of the scan rate-normalised cathodic peak current, , /V versus V, for cathodic peak II. The ratio /V for cathodic peak decreases severely with an increasing scan rate, indicating a CE mechanism in which the electrode reaction is gated by a slow preceding chemical step [15,26]. These results suggest that the two systems are not similar.…”
Section: Resultsmentioning
confidence: 90%
“…The modification and pretreatment of the working electrode were described elsewhere [15] as follow: the organic solution (1 L) was deposited on the graphite electrode with a micropipette; the organic solution spreads spontaneously over the electrode surface forming a stable film. The so-modified electrode was immersed in a phosphate buffer solution (0.1 M K 2 HPO 4 + 0.1 M KH 2 PO 4 ).…”
Section: Preparation Of the Filmmentioning
confidence: 99%
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“…In the recent study this approach was exploited to examine: electrochemical and spectroscopic behaviour of double-decker lutetium(III) phthalocyanines [4][5][6], the coupled electron-ion transfer reaction across liquid j liquid interface [2,[7][8][9] and the kinetic of the ion transfer across the liquid j liquid interface [10][11][12][13]. Generally for this study, an organic solvent is used, though most organic solvents are toxic and do not offer a wide range of electroactivity window.…”
Section: Introductionmentioning
confidence: 99%