The
COVID-19 lockdown has opened a unique window for investigating
aerosol formation and evolution with controlled anthropogenic emissions
in urban areas. Here, variations of PM2.5 chemical compositions,
gaseous pollutants, meteorological conditions, and secondary organic
aerosol (SOA) molecular tracers were monitored during three stages
at an urban site (Pudong) and a suburban site (Qingpu) in Shanghai,
which were defined as pre-COVID lockdown (PL), during COVID lockdown
(DL), and after COVID lockdown (AL) in 2020. Abundances of pollutants
during the same periods back in 2019 were also analyzed for a more
comprehensive intercomparison and evaluation of the impact of the
2020 COVID-19 lockdown on regional air quality. With the sudden cessation
of anthropogenic activities during the lockdown, significant reductions
in PM2.5 were observed compared to both PL in 2020 (32%
in Pudong and 36% in Qingpu) and the DL period back in 2019 (31% in
Pudong and 35% in Qingpu), which was accompanied by the significantly
reduced PM2.5 components (29–44% and 14–44%
reductions in sulfate, nitrate, ammonium, organic carbon, and elemental
carbon for Pudong and Qingpu, respectively). In particular, with the
reduced secondary inorganic aerosol (SIA), the time series of SOA
molecular tracers also underwent significant reduction that was characteristic
to the lockdown. Amid the uncontrolled biogenic emissions and even
slightly enhanced atmospheric oxidation capacity during the 2020 DL
period, controlling anthropogenic emissions exhibits synergistic effects
on the reduction of SIA and SOA, which could be further attributed
to the changes in the aerosol aqueous-phase environment, such as aerosol
liquid water content (ALWC), ionic strength, sulfate content, and
particulate NH4
+. Based on thermodynamic modeling,
greatly reduced ALWC was observed during 2020 DL, which can prevent
the partitioning of oxygenated organics into the condensed phase as
well as the aqueous-phase formation of SOA. Higher ionic strength
in 2020 DL may have a “salting-out” effect on gas–particle
partitioning of oxygenated organics. The reduced SOA during 2020 DL
at both sites can generally be reflected by the predicted heterogeneous
reaction kinetics (γ) of the isoprene SOA formation pathway.
Overall, our study showed a synergistic effect in suppressing SIA
and SOA formation upon the reduction of anthropogenic emissions during
the COVID-19 lockdown, which shed light on the importance of controlling
anthropogenic emissions in regulating secondary aerosol formation
in typical urban areas of East China.