With the relentless scaling of technology nodes, the track number reduction of conventional (Conv.) cell is starting to reach its limitations due to limited routing resources, lateral P-N separations, and performance requirements. As a result, to exploit the benefits of 3D architectures, Complementary-FET (CFET) technology, which stacks P-FET on N-FET or vice versa, is proposed to release the restriction of P-N separation and reduce in-cell routing congestion by enabling P-N direct connections. However, CFET standard cell (SDC) synthesis demands a holistic reconsideration of multi-row structure to maximize the cell and block-level area benefits due to limited in-cell routing tracks and routability that comes from the stacked structure and reduced cell height.In this paper, we propose an SMT (Satisfiability Modulo theories)-based Multi-Row CFET SDC synthesis framework that simultaneously solves place-and-route to minimize the cell area by considering single-row and multi-row placement together. We enable explorations on Upper/Lower M0A/PC routing to leverage the shared-and-split structure across cell rows with the proposed multi-row dynamic complementary pin allocation scheme. We demonstrate that multi-row 2.5T CFET without and with Upper/Lower M0A/PC routing achieve 16.44% and 20.61% on the average reduced cell areas, respectively, compared to 3.5T CFET. Moreover, multi-row 2.5T CFET SDCs achieve 13.43% and 14.40% less block-level area and total wirelength on average compared to 3.5T CFET SDCs.