J. Chem. Soc., Trans.

1925

DOI: 10.1039/ct9252701799

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CCXXXIX.—Bismuth dihydride

Edward Weeks¹,

J. G. F. Druce²

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Introduction2

B 13 C Isotopic Substitution2

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1949

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2014

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Cited by 6 publications

(7 citation statements)

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“…The overall chemical properties of s-Bill were found to be essentially the same as those of a material synthesized by a nonelectrochemical method (reduction of BP § ions in acid media with H2 evolution) described by Weeks and Druce in 1925, and proposed by these authors to be bismuth dihydride, Bi2H~ (17). To the best of our knowledge, the existence of this compound has since then not been verified.…”

Section: Resultssupporting

confidence: 55%

A Bismuth‐Based Electrocatalyst for the Chromous‐Chromic Couple in Acid Electrolytes

¹

,

²

,

³

et al. 1986

J. Electrochem. Soc.

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not Available.

“…The overall chemical properties of s-Bill were found to be essentially the same as those of a material synthesized by a nonelectrochemical method (reduction of BP § ions in acid media with H2 evolution) described by Weeks and Druce in 1925, and proposed by these authors to be bismuth dihydride, Bi2H~ (17). To the best of our knowledge, the existence of this compound has since then not been verified.…”

Section: Resultssupporting

confidence: 55%

A Bismuth‐Based Electrocatalyst for the Chromous‐Chromic Couple in Acid Electrolytes

¹

,

²

,

³

et al. 1986

J. Electrochem. Soc.

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not Available.

“…Weeks in the 1960s found that the Fe solubility decreases with increasing Pb fraction in liquid Pb-Bi. 19 This indicates that Bi has more severe corrosion capability than Pb, which was further proved by comparing the Ni and Cr solubility in liquid Pb and Pb-Bi alloy 19 and various steels in liquid Pb and Bi. 11,20 It is also found that Cr is corroded more easily than Fe in liquid Pb-Bi.…”

Section: Introductionmentioning

confidence: 84%

An energetic evaluation of dissolution corrosion capabilities of liquid metals on iron surface

¹

,

²

,

³

et al. 2014

Phys. Chem. Chem. Phys.

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Using first principles calculations, dissolution corrosion of liquid metals on iron surfaces has been investigated by calculating adsorption energies of metal atoms in the liquid phase on the surface and escape energies of surface Fe atoms. The adsorption energies, characterizing the stability of the adsorbed atoms on the investigated surfaces, show that Bi is more stable than Pb and Au. The escape energies, representing the energy required for an Fe atom to escape from the surface, show that adsorbed Pb makes surface Fe atoms escape more easily than Bi and Au. The combination of adsorption energy and escape energy indicates that the corrosion capabilities of liquid metals decrease in the order Bi > Pb > Au. This is further proved by the investigation of surface properties, such as inter-layer distance, magnetic momentum and charge density difference. The results are consistent with experimental results that Fe can be corroded more severely in Bi than in Pb. In the case of liquid alloys, chemical proportions of compositions are incorporated to evaluate the corrosion capabilities of Pb-Bi eutectic (LBE) and Pb-Au eutectic (LGE). It is found that LBE has more severe corrosion capability than LGE. The energetic calculation is further developed in evaluating the effect of alloying elements in popular steels on the dissolution corrosion. The results indicate that Si, V, Nb and Mo may mitigate the dissolution corrosion of martensite steels in liquid Pb, Bi and Au.

“…In contrast to icosahedral 12 C 60 , the 13 C 12 C 59 molecule has only C, symmetry, 23 and its rotational levels are those of a slightly prolate symmetric top, without the strict bosonicexchange exclusion. 23 ' 24 The extra neutron also lifts the three-fold degeneracy of the four F lu vibrational modes 14 by amounts ranging from * 0.5 to over 2 cm' 1 . For 13 " n n r^6°-n (3)-P(P,n) = ---:…”

Section: B 13 C Isotopic Substitutionmentioning

confidence: 99%

High-Resolution Infrared Absorption Spectroscopy of C₆₀ Molecules and Clusters in Parahydrogen Solids

Kato²,

et al. 2000

J. Phys. Chem. A

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