“…[3,4] In scanning electron microscopy(SEM) caustics can also appear but are treated as inconvenient obstructions to viewing nanoparticles. [5] Gold particles as small as 5 nm were observed using light scattering more than a century ago by Zsigmondy [6] and more recently, Berciaud et al [7] have recorded absorption spectra for such particles. In direct far-field observation, diffraction at a small aperture is known to produce a bright spot known as an Airy disc surrounded by fainter bright rings whilst, conversely, an opaque circular disc generates essentially the negative of this, with the exception of very small, bright circular spot at the center of the pattern, known as Poisson's spot.…”