volume 9, issue 1, P163-174 1971
DOI: 10.1002/pol.1971.150090115
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Abstract: Abstract cis‐ and trans‐1‐Ethoxy‐1,3‐butadienes were polymerized by a variety of cationic agents in various solvents at −78°C. The trans ether, which is the more stable isomer, was found to have greater polymerizability than the cis ether. The trans monomer gave polymers predominantly of the trans‐1,4 type, whereas the cis monomer showed a tendency toward the formation of polymers having the microstructure of the 1,2 type. It was concluded that, in the cis ether, the carbon atom which is the most vulnerable t…

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