Catalytic Pauson–Khand reaction in ionic liquids

Mastrorilli, Piero; Nobile, Cosimo Francesco; Paolillo, Rossella; Suranna, Gian Paolo

doi:10.1016/j.molcata.2003.11.033

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13 Pauson−khand Reaction1

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Cited by 23 publications

(2 citation statements)

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“…The ILs [C 4 mim][PF 6 ] and [C 4 mim][BF 4 ] have been shown to allow the Co 2 (CO) 8 -catalyzed intramolecular and intermolecular Pauson−Khand annelation (Scheme ) . In this case, a pressure of CO of at least 10 bar was required with diethyl allyl propargyl malonates showing quantitative conversion in the corresponding cyclopentenones.…”

Section: 13 Pauson−khand Reactionmentioning

confidence: 99%

Catalysis in Ionic Liquids

2007

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Pa ˆrvulescu and Hardacre Scheme 80. Thioacetalization and Transthioacetalization of Aromatic Aldehydes Scheme 81. Ethylenediammonium-Diacetate-Catalyzed Gewald Synthesis of 2-Aminothiophenes Scheme 82. Preparation of Bis-indolylmethanes through Electrophilic Substitution Reactions of Indoles with Aldehydes and Ketones in ILs Scheme 83. Conversion of Ethyl Cyclohexanone-2-carboxylate to Methyl Vinyl Ketone

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Section: 13 Pauson−khand Reactionmentioning

confidence: 99%

Catalysis in Ionic Liquids

2007

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“…As solvents, ionic liquids have found applications in a number of reactions [6][7][8][9][10][11][12][13][14][15][16]. Dupont et al extensively reviewed the application of ionic liquids as catalytic phase in various organometallic reactions [17].…”

Section: Introductionmentioning

confidence: 99%

Ionic Liquids: Synthesis and Applications in Catalysis

Rajni

2014

Advances in Chemistry

210

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Ionic liquids have emerged as an environmentally friendly alternative to the volatile organic solvents. Being designer solvents, they can be modulated to suit the reaction conditions, therefore earning the name "task specific ionic liquids. " Though primarily used as solvents, they are now finding applications in various fields like catalysis, electrochemistry, spectroscopy, and material science to mention a few. The present review is aimed at exploring the applications of ionic liquids in catalysis as acid, base, and organocatalysts and as soluble supports for catalysts.

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Five‐Membered Carbocycles

2010

Name Reactions for Carbocyclic Ring Formations

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Catalytic Pauson–Khand reaction in ionic liquids

Cited by 23 publications

References 38 publications

Catalysis in Ionic Liquids

Catalysis in Ionic Liquids

Ionic Liquids: Synthesis and Applications in Catalysis

Five‐Membered Carbocycles

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